Nickel dimethyldithiocarbamate

Base Information

• Chemical Name: Nickel dimethyldithiocarbamate
• CAS No.: 15521-65-0
• Molecular Formula: C6H12N2NiS4
• Molecular Weight: 299.129
• Hs Code.: 2930909090
• European Community (EC) Number: 239-560-8
• Wikipedia: Nickel_bis(dimethyldithiocarbamate)
• Mol file: 15521-65-0.mol

Synonyms:Nickel dimethyldithiocarbamate;Nickel bis(dimethyldithiocarbamate);N,N-dimethylcarbamodithioate;nickel(2+);N,N-Dimethyldithiocarbamate nickel;AKOS015913868

Chemical Property of Nickel dimethyldithiocarbamate

Chemical Property:

• Appearance/Colour: COA
• Vapor Pressure: 10.2mmHg at 25°C
• Melting Point: >290 °C
• Boiling Point: 129.4 °C at 760 mmHg
• Flash Point: 32 °C
• PSA: 121.26000
• Density: 1.77 g/cm³
• LogP: 2.06080
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 297.923675
• Heavy Atom Count: 13
• Complexity: 143

Purity/Quality:

99% ^*data from raw suppliers

NICKEL DIMETHYLDITHIOCARBAMATE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 20/21/22
• Safety Statements: 22-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C)C(=S)[S-].CN(C)C(=S)[S-].[Ni+2]

Technology Process of Nickel dimethyldithiocarbamate

There total 5 articles about Nickel dimethyldithiocarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

nickel (7440-02-0) + sodium dimethyldithiocarbamate (128-04-1) → bis(N,N-dimethyldithiocarbamate)nickel(II) (15521-65-0)

Guidance literature:

In chloroform; addn. of Ni powder to a suspension of the dithiocarbamate in CHCl3; stirring for 5 h;; filtration; the filtrate was washed 5 times with water; concn. of the organic soln.; recrystn. twice from CHCl3; elem. anal.;; Kinetics;

DOI:10.1016/S0277-5387(00)84424-1

Reference yield:

Ni((CH3)2NCS2)3(1+)*NO3(1-) = [Ni((CH3)2NCS2)3]NO3 (83202-02-2) → bis(N,N-dimethyldithiocarbamate)nickel(II) (15521-65-0)

Guidance literature:

In acetonitrile; byproducts: Ni(2+), (Me2NCS2)2; Irradiation (UV/VIS); irradiated (poly- (425-670 nm) and mono- (436 nm) chromatically); photometry; Kinetics;

Reference yield:

Ni((CH3)2NCS2)3(1+)*BF4(1-) = [Ni((CH3)2NCS2)3]BF4 (63576-43-2) → bis(N,N-dimethyldithiocarbamate)nickel(II) (15521-65-0)

Guidance literature:

In acetonitrile; byproducts: Ni(2+), (Me2NCS2)2; Irradiation (UV/VIS); irradiated (poly- (425-670 nm) and mono- (436 nm) chromatically); photometry; Kinetics;

upstream raw materials:

Thiram

nickel

sodium dimethyldithiocarbamate

Ni((CH₃)2NCS₂)3⁽¹⁺⁾*NO₃^(1-) = [Ni((CH₃)2NCS₂)3]NO₃

Refernces

• 1、 Geloso, Corrado,Kumar, Rajesh,Lopez-Grado, Jaime Romero,Tuck, Dennis G.. "THE DIRECT ELECTROCHEMICAL SYNTHESIS OF DIALKYLDITHIOCARBAMATE AND DIETHYLDITHIOPHOSPHATE COMPLEXES OF MAIN GROUP AND TRANSITION METALS". . p. 928 - 932. Retrieved 2007/10/02.