(pentafluorophenyl)ylmethyl sulfamate

Base Information

• Chemical Name: (pentafluorophenyl)ylmethyl sulfamate
• CAS No.: 1306748-10-6
• Molecular Formula: C₇H₄F₅NO₃S
• Molecular Weight: 277.172
• Mol file: 1306748-10-6.mol

Synonyms:(pentafluorophenyl)ylmethyl sulfamate

Chemical Property of (pentafluorophenyl)ylmethyl sulfamate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (pentafluorophenyl)ylmethyl sulfamate

There total 2 articles about (pentafluorophenyl)ylmethyl sulfamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

isocyanate de chlorosulfonyle (1189-71-5) + (2,3,4,5,6-pentafluorophenyl)methanol (440-60-8) → (pentafluorophenyl)ylmethyl sulfamate (1306748-10-6)

Guidance literature:

isocyanate de chlorosulfonyle; With formic acid; In acetonitrile; at 0 ℃; for 3.5h; Inert atmosphere;

(2,3,4,5,6-pentafluorophenyl)methanol; In N,N-dimethyl acetamide; acetonitrile; at 0 - 20 ℃; for 3.5h; Inert atmosphere;

DOI:10.1002/anie.201902882

Reference yield: 54.0%

(2,3,4,5,6-pentafluorophenyl)methanol (440-60-8) → (pentafluorophenyl)ylmethyl sulfamate (1306748-10-6)

Guidance literature:

With sulphamoyl chloride; In N,N-dimethyl acetamide; at 20 ℃; for 24h;

DOI:10.1002/ejoc.201100054

Reference yield: 79.0%

(pentafluorophenyl)ylmethyl sulfamate (1306748-10-6) + Cyclohex-2-enol (822-67-3) → (pentafluorophenyl)methyl N-(cyclohex-2-en-1-yl)sulfamate (1306748-16-2)

Guidance literature:

With mercuric triflate; In dichloromethane; at 20 ℃; for 4h;

DOI:10.1002/ejoc.201100054

upstream raw materials:

(2,3,4,5,6-pentafluorophenyl)methanol

isocyanate de chlorosulfonyle

Downstream raw materials:

(pentafluorophenyl)methyl N-(cyclohex-2-en-1-yl)sulfamate