(E)-tert-butyl((6-(4-(tert-butyl)phenyl)-3-methylhex-3-en-1-yl)oxy)dimethylsilane

Base Information

• Chemical Name: (E)-tert-butyl((6-(4-(tert-butyl)phenyl)-3-methylhex-3-en-1-yl)oxy)dimethylsilane
• CAS No.: 1222923-40-1
• Molecular Formula: C₂₃H₄₀OSi
• Molecular Weight: 360.656
• Mol file: 1222923-40-1.mol

Synonyms:(E)-tert-butyl((6-(4-(tert-butyl)phenyl)-3-methylhex-3-en-1-yl)oxy)dimethylsilane

Chemical Property of (E)-tert-butyl((6-(4-(tert-butyl)phenyl)-3-methylhex-3-en-1-yl)oxy)dimethylsilane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-tert-butyl((6-(4-(tert-butyl)phenyl)-3-methylhex-3-en-1-yl)oxy)dimethylsilane

There total 1 articles about (E)-tert-butyl((6-(4-(tert-butyl)phenyl)-3-methylhex-3-en-1-yl)oxy)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

4-tert-Butylstyrene (1746-23-2,26009-55-2) + (E)-4-tert-butyldimethylsilyloxy-1-iodo-2-methyl-1-butene (78592-77-5) → (E)-tert-butyl((6-(4-(tert-butyl)phenyl)-3-methylhex-3-en-1-yl)oxy)dimethylsilane (1222923-40-1)

Guidance literature:

4-tert-Butylstyrene; With 9-bora-bicyclo[3.3.1]nonane; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;

(E)-4-tert-butyldimethylsilyloxy-1-iodo-2-methyl-1-butene; With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; sodium hydroxide; In tetrahydrofuran; water; at 0 - 4 ℃; Inert atmosphere;

DOI:10.1021/ja101256v

Reference yield: 91.0%

(E)-tert-butyl((6-(4-(tert-butyl)phenyl)-3-methylhex-3-en-1-yl)oxy)dimethylsilane (1222923-40-1) → (E)-6-(4-(tert-butyl)phenyl)-3-methylhex-3-en-1-ol (1222923-55-8)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃;

DOI:10.1021/ja101256v

upstream raw materials:

4-tert-Butylstyrene

(E)-4-tert-butyldimethylsilyloxy-1-iodo-2-methyl-1-butene

Downstream raw materials:

(E)-6-(4-(tert-butyl)phenyl)-3-methylhex-3-en-1-ol