Silane, (1,1-dimethylethyl)(((3E)-4-iodo-3-methyl-3-buten-1-yl)oxy)dimethyl-

Base Information

• Chemical Name: Silane, (1,1-dimethylethyl)(((3E)-4-iodo-3-methyl-3-buten-1-yl)oxy)dimethyl-
• CAS No.: 78592-77-5
• Deprecated CAS: 1344153-71-4
• Molecular Formula: C11H23IOSi
• Molecular Weight: 326.293
• Nikkaji Number: J1.138.185E,J2.826.650B
• Mol file: 78592-77-5.mol

Synonyms:Silane, (1,1-dimethylethyl)(((3E)-4-iodo-3-methyl-3-buten-1-yl)oxy)dimethyl-;78592-77-5;1-Iodo-2-methyl-4-(tert-butyldimethylsiloxy)-1-butene;(E)-1-Iodo-2-methyl-4-(tert-butyldimethylsiloxy)-1-butene

Chemical Property of Silane, (1,1-dimethylethyl)(((3E)-4-iodo-3-methyl-3-buten-1-yl)oxy)dimethyl-

Chemical Property:

• Vapor Pressure: 0.0124mmHg at 25°C
• Boiling Point: 268.8°C at 760 mmHg
• Flash Point: 116.4°C
• Density: 1.233g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 326.05629
• Heavy Atom Count: 14
• Complexity: 204

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=CI)CCO[Si](C)(C)C(C)(C)C
• Isomeric SMILES: C/C(=C\I)/CCO[Si](C)(C)C(C)(C)C

Technology Process of Silane, (1,1-dimethylethyl)(((3E)-4-iodo-3-methyl-3-buten-1-yl)oxy)dimethyl-

There total 3 articles about Silane, (1,1-dimethylethyl)(((3E)-4-iodo-3-methyl-3-buten-1-yl)oxy)dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

t-butyldimethylsiyl triflate (69739-34-0) + (E)-4-iodo-3-methylbut-3-en-1-ol (78592-73-1) → (E)-4-tert-butyldimethylsilyloxy-1-iodo-2-methyl-1-butene (78592-77-5)

Guidance literature:

With 2,6-dimethylpyridine; In dichloromethane; at -78 ℃;

DOI:10.1055/s-2007-980367

Reference yield: 98.0%

(E)-4-iodo-3-methylbut-3-en-1-ol (78592-73-1) + tert-butyldimethylsilyl chloride (18162-48-6) → (E)-4-tert-butyldimethylsilyloxy-1-iodo-2-methyl-1-butene (78592-77-5)

Guidance literature:

With dmap; triethylamine; In dichloromethane; at 0 - 20 ℃; for 70h;

DOI:10.1039/b307985f

Reference yield:

4-(tert-butyldimethylsilyloxy)-1-butyne (78592-82-2) + trimethylaluminum (75-24-1) → (E)-4-tert-butyldimethylsilyloxy-1-iodo-2-methyl-1-butene (78592-77-5)

Guidance literature:

With iodine; zirconocene dichloride; Yield given. Multistep reaction;

DOI:10.1021/jo00333a041

upstream raw materials:

4-(tert-butyldimethylsilyloxy)-1-butyne

trimethylaluminum

(E)-4-iodo-3-methylbut-3-en-1-ol

tert-butyldimethylsilyl chloride

Downstream raw materials:

C₂₇H₄₆O₄Si

(E)-tert-butyl((6-(4-(tert-butyl)phenyl)-3-methylhex-3-en-1-yl)oxy)dimethylsilane

(E)-tert-butyldimethyl(3-methyl-(6-(p-tolyl)hex-3-en-1-yl)oxy)silane

(E)-tert-butyl((6-(4-methoxyphenyl)-3-methylhex-3-en-1-yl)oxy)dimethylsilane