PtH(SeTrip)(PPh₃)2

Base Information

• Chemical Name: PtH(SeTrip)(PPh₃)2
• CAS No.: 1032197-97-9
• Molecular Formula: C₅₆H₄₄P₂PtSe
• Molecular Weight: 1052.95
• Mol file: 1032197-97-9.mol

Synonyms:PtH(SeTrip)(PPh₃)2

Chemical Property of PtH(SeTrip)(PPh₃)2

Chemical Property:

Purity/Quality:

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Technology Process of PtH(SeTrip)(PPh₃)2

There total 1 articles about PtH(SeTrip)(PPh₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

ethylenebis(triphenylphosphine)platinum(0) (12120-15-9) + 9-trypticeneselenol (220917-90-8) → PtH(SeTrip)(PPh3)2 (1032197-97-9)

Guidance literature:

In dichloromethane; treatment of selenol deriv. with platinum compd. in CH2Cl2 at room temp.;

DOI:10.1002/anie.200705336

Reference yield: 60.0%

PtH(SeTrip)(PPh3)2 (1032197-97-9) → [Pt(SeTrip(-H))(triphenylphosphane)2]*dichloromethane

Guidance literature:

With HBF₄; In not given; treatment of platinum compd. with HBF4;

DOI:10.1002/anie.200705336

Reference yield: 36.0%

PtH(SeTrip)(PPh3)2 (1032197-97-9) + propynoic acid methyl ester (922-67-8) → methyl (E)-3-(9-triptycylseleno)propenoate (1226794-67-7) + C57H44P2PtSe + di-9-triptycyl diselenide (105862-36-0)

Guidance literature:

In benzene; at 60 ℃; for 3h; stereoselective reaction; Mechanism; Inert atmosphere;

DOI:10.1002/ejoc.200901408

upstream raw materials:

ethylenebis(triphenylphosphine)platinum⁽⁰⁾

9-trypticeneselenol

Downstream raw materials:

methyl (E)-3-(9-triptycylseleno)propenoate

di-9-triptycyl diselenide

(E)-dimethyl 2-(9-triptycylseleno)maleate