Fluazifop-P-butyl

Base Information

• Chemical Name: Fluazifop-P-butyl
• CAS No.: 79241-46-6
• Molecular Formula: C19H20F3NO4
• Molecular Weight: 383.367
• Hs Code.: 29333990
• European Community (EC) Number: 616-669-2
• UNII: N99K0AJ91S
• DSSTox Substance ID: DTXSID0034855
• Nikkaji Number: J491.291H
• Wikidata: Q1430447
• ChEMBL ID: CHEMBL1864569
• Mol file: 79241-46-6.mol

Synonyms:FLUAZIFOP-P-BUTYL;79241-46-6;Fusilade super;Fusilade 2000;Fusilade S;Fusilade DX;Fusilade II;Fusilade 5;PP005 2E Herbicide;Fluazifop-P-butyl [ISO];butyl (2R)-2-[4-[5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoate;PP 005;EPA Pesticide Chemical Code 122809;UNII-N99K0AJ91S;N99K0AJ91S;DTXSID0034855;Butyl (R)-2-[4-(5-trifluoromethyl-2-pyridyloxy)phenoxy]propionate;Propanoic acid, 2-[4-[[5-(trifluoromethyl)-2-pyridinyl]oxy]phenoxy]-, butylester, (2R)-;Fluazifop-P-butyl 10 microg/mL in Acetone;Butyl (R)-2-(4-(5-trifluoromethyl)-2-pyridyloxy)phenoxypropionate;butyl (2R)-2-(4-{[5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoate;Butyl (R)-2-(4-((5-(trifluoromethyl)-2-pyridinyl)oxy)phenoxy)propanoate;BRN 1510062;Propanoic acid, 2-(4-((5-(trifluoromethyl)-2-pyridinyl)oxy)phenoxy)-, butyl ester, (2R)-;Propanoic acid, 2-(4-((5-(trifluoromethyl)-2-pyridinyl)oxy)phenoxy)-, butyl ester, (R)-;Fluazifop-P butyl ester;C19-H20-F3-N-O4;Fluazafop-P-butyl;Propanoic acid, 2-[4-[[5-(trifluoromethyl)-2-pyridinyl]oxy]phenoxy]-, butyl ester, (2R)-;Propanoic acid, 2-[4-[[5-(trifluoromethyl)-2-pyridinyl]oxy]phenoxy]-, butyl ester, (R)-;FUSILADE FORTE;SCHEMBL55176;BIDD:ER0605;CHEMBL1864569;DTXCID8014855;CHEBI:132964;VAIZTNZGPYBOGF-CYBMUJFWSA-N;HY-B2007;Tox21_301193;AKOS015896007;butyl (2R)-2-[4-[[5-(trifluoromethyl)-2-pyridyl]oxy]phenoxy]propanoate;NCGC00163739-01;NCGC00163739-02;NCGC00163739-03;NCGC00164281-01;NCGC00255091-01;AS-83737;CAS-79241-46-6;LS-121608;CS-0014108;EN300-7482582;Fluazifop-P-butyl 100 microg/mL in Acetonitrile;A839625;Q-101459;Q1430447;Fluazifop-P-butyl, PESTANAL(R), analytical standard;Z3234883621;(R)-Butyl 2-(4-((5-(trifluoromethyl)pyridin-2-yl)oxy)phenoxy)propanoate;(R)-butyl 2-(4-(5-(trifluoromethyl)pyridin-2-yloxy)phenoxy)propanoate;butyl (2R)-2-[4-[[5-(trifluoromethyl)-2-pyridinyl]oxy]phenoxy]propanoate;butyl (R)-2-{4-[5-(trifluoromethyl)-2-pyridyloxy]phenoxy}propionate

Chemical Property of Fluazifop-P-butyl

Chemical Property:

• Appearance/Colour: light yellow liquid
• Vapor Pressure: 8.36E-08mmHg at 25°C
• Melting Point: 5 °C
• Refractive Index: 1.498
• Boiling Point: 436 °C at 760 mmHg
• PKA: 0.78±0.22(Predicted)
• Flash Point: 217.5 °C
• PSA: 57.65000
• Density: 1.222 g/cm³
• LogP: 5.00330
• Storage Temp.: 0-6°C
• Water Solubility.: 1 mg/L at 25 ºC
• XLogP3: 4.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 9
• Exact Mass: 383.13444261
• Heavy Atom Count: 27
• Complexity: 453

Purity/Quality:

99% ^*data from raw suppliers

Fluazifop-P-butyl(~90%) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn,N
• Hazard Codes: Xn;N,N,Xn
• Statements: 50/53-63
• Safety Statements: 2-29-36/37-46-60-61

MSDS Files:

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCOC(=O)C(C)OC1=CC=C(C=C1)OC2=NC=C(C=C2)C(F)(F)F
• Isomeric SMILES: CCCCOC(=O)[C@@H](C)OC1=CC=C(C=C1)OC2=NC=C(C=C2)C(F)(F)F

Technology Process of Fluazifop-P-butyl

There total 2 articles about Fluazifop-P-butyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

2-fluoro-5-(trifluoromethyl)pyridine (69045-82-5) + (R)-2-(4-hydroxyphenoxy)propionic acid (94050-90-5) + butan-1-ol (71-36-3) → butyl (R)-2-[4-[(5-(trifluoromethyl)-2-pyridinyl)oxy]-phenoxy]propanoate (79241-46-6,79241-47-7)

Guidance literature:

2-fluoro-5-(trifluoromethyl)pyridine; (R)-2-(4-hydroxyphenoxy)propionic acid; With potassium phosphate; tetra-(n-butyl)ammonium iodide; In N,N-dimethyl-formamide; at 50 - 60 ℃; for 2h;

With 1,3,5-trichloro-2,4,6-triazine; In N,N-dimethyl-formamide; at 5 - 25 ℃; for 1.16667h;

butan-1-ol; In N,N-dimethyl-formamide;

DOI:10.4067/S0717-97072011000400002

Reference yield: 30.0%

→ butyl (R)-2-[4-[(5-(trifluoromethyl)-2-pyridinyl)oxy]-phenoxy]propanoate (79241-46-6,79241-47-7)

Guidance literature:

upstream raw materials:

2-fluoro-5-(trifluoromethyl)pyridine

(R)-2-(4-hydroxyphenoxy)propionic acid

butan-1-ol

Refernces

• 1、 -. "Water dispersible granules of liquid pesticides". . . Retrieved 2008/06/13.