2-trifluorophenyl 3,4,6-tri-O-acetyl-2-deoxy-2-o-trifluoromethylbenzylideneamino-α-D-glucopyranosyl-(1→4)-2,3-di-O-isopropylidene-1-thiol-α-L-rhamnopyranoside

Base Information

Chemical Name:2-trifluorophenyl 3,4,6-tri-O-acetyl-2-deoxy-2-o-trifluoromethylbenzylideneamino-α-D-glucopyranosyl-(1→4)-2,3-di-O-isopropylidene-1-thiol-α-L-rhamnopyranoside
CAS No.:1391598-29-0
Molecular Formula:C₃₆H₃₉F₆NO₁₁S
Molecular Weight:807.762
Hs Code.:

2-trifluorophenyl 3,4,6-tri-O-acetyl-2-deoxy-2-o-trifluoromethylbenzylideneamino-α-D-glucopyranosyl-(1→4)-2,3-di-O-isopropylidene-1-thiol-α-L-rhamnopyranoside

Synonyms:2-trifluorophenyl 3,4,6-tri-O-acetyl-2-deoxy-2-o-trifluoromethylbenzylideneamino-α-D-glucopyranosyl-(1→4)-2,3-di-O-isopropylidene-1-thiol-α-L-rhamnopyranoside

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Chemical Property of 2-trifluorophenyl 3,4,6-tri-O-acetyl-2-deoxy-2-o-trifluoromethylbenzylideneamino-α-D-glucopyranosyl-(1→4)-2,3-di-O-isopropylidene-1-thiol-α-L-rhamnopyranoside

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Technology Process of 2-trifluorophenyl 3,4,6-tri-O-acetyl-2-deoxy-2-o-trifluoromethylbenzylideneamino-α-D-glucopyranosyl-(1→4)-2,3-di-O-isopropylidene-1-thiol-α-L-rhamnopyranoside

There total 2 articles about 2-trifluorophenyl 3,4,6-tri-O-acetyl-2-deoxy-2-o-trifluoromethylbenzylideneamino-α-D-glucopyranosyl-(1→4)-2,3-di-O-isopropylidene-1-thiol-α-L-rhamnopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 1391597-81-1
C₁₆H₁₉F₃O₄S

: 3,4,6-tri-O-acetyl-2-deoxy-2-otrifluoromethylbenzylideneamino-D-glucopyranosyl N-phenyl trifluoroacetimidate

: 1391598-29-0
2-trifluorophenyl 3,4,6-tri-O-acetyl-2-deoxy-2-o-trifluoromethylbenzylideneamino-α-D-glucopyranosyl-(1→4)-2,3-di-O-isopropylidene-1-thiol-α-L-rhamnopyranoside

Guidance literature:: With Ni(4-F-PhCN)₄(OTf)₂; In dichloromethane; at 35 ℃; for 14h; stereoselective reaction;
DOI:10.1021/jo301050q

Reference yield: 93.0%

: 1391597-81-1
C₁₆H₁₉F₃O₄S

: 1391597-82-2
3,4,6-tri-O-acetyl-2-deoxy-2-otrifluoromethylbenzylideneamino-D-glucopyranosyl N-phenyl trifluoroacetimidate

: 1391598-29-0
2-trifluorophenyl 3,4,6-tri-O-acetyl-2-deoxy-2-o-trifluoromethylbenzylideneamino-α-D-glucopyranosyl-(1→4)-2,3-di-O-isopropylidene-1-thiol-α-L-rhamnopyranoside

Guidance literature:: With nickel(II) triflate; In dichloromethane; at 35 ℃; for 16h; Inert atmosphere;
DOI:10.1016/j.carres.2016.10.008

Reference yield:

: 1391598-29-0
2-trifluorophenyl 3,4,6-tri-O-acetyl-2-deoxy-2-o-trifluoromethylbenzylideneamino-α-D-glucopyranosyl-(1→4)-2,3-di-O-isopropylidene-1-thiol-α-L-rhamnopyranoside

: 4064-06-6
1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

: 1391598-46-1
3,4,6-tri-O-acetyl-2-deoxy-2-o-trifluoromethylbenzylideneamino-α-D-glucopyranosyl-(1→4)-2,3-di-O-isopropylidene-L-rhamnopyranosyl-(1→6)-1,2,3,4-bis-(di-O-isopropylidene)-α-D-galactopyranoside

: 1391598-45-0
3,4,6-tri-O-acetyl-2-deoxy-2-o-trifluoromethylbenzylideneamino-α-D-glucopyranosyl-(1→4)-2,3-di-O-isopropylidene-L-rhamnopyranosyl-(1→6)-1,2,3,4-bis-(di-O-isopropylidene)-α-D-galactopyranoside

Guidance literature:: 2-trifluorophenyl 3,4,6-tri-O-acetyl-2-deoxy-2-o-trifluoromethylbenzylideneamino-α-D-glucopyranosyl-(1→4)-2,3-di-O-isopropylidene-1-thiol-α-L-rhamnopyranoside; 1,2:3,4-di-O-isopropylidene-α-D-galactopyranose; In dichloromethane; at 20 ℃; for 1h; Molecular sieve; Inert atmosphere;

With N-iodo-succinimide; In dichloromethane; at -78 - 20 ℃; for 0.333333h; Inert atmosphere;

With silver trifluoromethanesulfonate; In dichloromethane; at 0 - 35 ℃; Overall yield = 85 %; Overall yield = 15 mg; Inert atmosphere;
DOI:10.1021/jo301050q