2(C₂H₅)4N⁽¹⁺⁾*Fe₄(SC₆H₅)10^(2-)=[(C₂H₅)4N]2[Fe₄(SC₆H₅)10]

Base Information

• Chemical Name: 2(C₂H₅)4N⁽¹⁺⁾*Fe₄(SC₆H₅)10^(2-)=[(C₂H₅)4N]2[Fe₄(SC₆H₅)10]
• CAS No.: 78318-86-2
• Molecular Formula: 2C₈H₂₀N*C₆₀H₅₀Fe₄S₁₀
• Molecular Weight: 1575.61
• Mol file: 78318-86-2.mol

Synonyms:2(C₂H₅)4N⁽¹⁺⁾*Fe₄(SC₆H₅)10^(2-)=[(C₂H₅)4N]2[Fe₄(SC₆H₅)10]

Chemical Property of 2(C₂H₅)4N⁽¹⁺⁾*Fe₄(SC₆H₅)10^(2-)=[(C₂H₅)4N]2[Fe₄(SC₆H₅)10]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2(C₂H₅)4N⁽¹⁺⁾*Fe₄(SC₆H₅)10^(2-)=[(C₂H₅)4N]2[Fe₄(SC₆H₅)10]

There total 3 articles about 2(C₂H₅)4N⁽¹⁺⁾*Fe₄(SC₆H₅)10^(2-)=[(C₂H₅)4N]2[Fe₄(SC₆H₅)10] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

iron(III) chloride hexahydrate (121714-78-1,24290-40-2,58694-80-7,10025-77-1,64333-00-2) + tetraethylammonium bromide (71-91-0) + sodium thiophenolate (930-69-8) → 2(C2H5)4N(1+)*Fe4(SC6H5)10(2-)=[(C2H5)4N]2[Fe4(SC6H5)10] (78318-86-2)

Guidance literature:

In ethanol; byproducts: NaCl, NaBr; under anaerobic conditions; addn. of soln. of FeCl3 to stirred soln. of NaSPh, after 5 min addn. of soln. of Et4NBr; cooling to -20°C, filtration, washing with ethanol; for removal of NaCl and NaBr dissolving in acetonitrile, filtration, pptn. by addn. of ethanol, cooling to -20°C, filtration, washing with ethanol, drying in vac.; elem. anal.;

DOI:10.1021/ja00404a013

Reference yield: 76.0%

iron(II) chloride dihydrate + tetraethylammonium bromide (71-91-0) + sodium thiophenolate (930-69-8) → 2(C2H5)4N(1+)*Fe4(SC6H5)10(2-)=[(C2H5)4N]2[Fe4(SC6H5)10] (78318-86-2)

Guidance literature:

In ethanol; byproducts: NaCl, NaBr; under anaerobic conditions; addn. of soln. of FeCl2 to stirred soln. of NaSPh, addn. of soln. of Et4NBr, stirring; filtration, washing with isoprpyl alcohol, dissolving in acetonitrile, filtration, pptn. by addn. of warm ethanol, filtration, washing with isopropyl alcohol/acetonitrile then ether, drying in vac.;

DOI:10.1021/ja00404a013

Reference yield: 76.0%

iron(III) chloride hexahydrate (121714-78-1,24290-40-2,58694-80-7,10025-77-1,64333-00-2) + tetraethylammonium bromide (71-91-0) + thiophenol (108-98-5) → 2(C2H5)4N(1+)*Fe4(SC6H5)10(2-)=[(C2H5)4N]2[Fe4(SC6H5)10] (78318-86-2)

Guidance literature:

With lithium hydroxide; In water; acetonitrile; addn. of PhSH to a slurry of FeCl3*6H2O in CH3CN; addn. of the soln. toTriton X-100; addn. of the soln. to a stirred mixt. of LiOH*H2O and (C2H5)4NBr in H2O at pH 8.7; stirring at room temp. for 8-9 h; Ar atm.;;

upstream raw materials:

tetraethylammonium bromide

sodium thiophenolate

iron(III) chloride hexahydrate

thiophenol