Technology Process of methyl-(2S,3S,4R,5R,6S)-N-benzyl-4,6-bis(tert-butyldimethylsilyloxy)-2,3-dihydroxy-5,7-iminoheptanoate
There total 4 articles about methyl-(2S,3S,4R,5R,6S)-N-benzyl-4,6-bis(tert-butyldimethylsilyloxy)-2,3-dihydroxy-5,7-iminoheptanoate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
potassium osmate(VI); methanesulfonamide; potassium carbonate; hydroquinidein 1,4-phthalazinediyl diether; potassium hexacyanoferrate(III);
In
water; tert-butyl alcohol;
at 20 ℃;
for 24h;
DOI:10.1016/j.bmc.2013.03.004
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: sodium hydroxide / water; dichloromethane / 0.25 h
1.2: 16 h / 20 °C
2.1: 2,6-dimethylpyridine / N,N-dimethyl-formamide / 22 h / 20 °C
3.1: potassium hexacyanoferrate(III); potassium carbonate; methanesulfonamide; potassium osmate(VI); hydroquinidein 1,4-phthalazinediyl diether / water; tert-butyl alcohol / 24 h / 20 °C
With
2,6-dimethylpyridine; potassium osmate(VI); methanesulfonamide; potassium carbonate; hydroquinidein 1,4-phthalazinediyl diether; sodium hydroxide; potassium hexacyanoferrate(III);
In
dichloromethane; water; N,N-dimethyl-formamide; tert-butyl alcohol;
DOI:10.1016/j.bmc.2013.03.004
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: trifluoroacetic acid / water / 24 h / 20 °C
2.1: sodium hydroxide / water; dichloromethane / 0.25 h
2.2: 16 h / 20 °C
3.1: 2,6-dimethylpyridine / N,N-dimethyl-formamide / 22 h / 20 °C
4.1: potassium hexacyanoferrate(III); potassium carbonate; methanesulfonamide; potassium osmate(VI); hydroquinidein 1,4-phthalazinediyl diether / water; tert-butyl alcohol / 24 h / 20 °C
With
2,6-dimethylpyridine; potassium osmate(VI); methanesulfonamide; potassium carbonate; hydroquinidein 1,4-phthalazinediyl diether; trifluoroacetic acid; sodium hydroxide; potassium hexacyanoferrate(III);
In
dichloromethane; water; N,N-dimethyl-formamide; tert-butyl alcohol;
DOI:10.1016/j.bmc.2013.03.004
