(2E)-methyl-(4S,5S,6S)-N-benzyl-4,6-bis(tert-butyldimethylsilyloxy)-5,7-iminohept-2-enoate

Base Information

Chemical Name:(2E)-methyl-(4S,5S,6S)-N-benzyl-4,6-bis(tert-butyldimethylsilyloxy)-5,7-iminohept-2-enoate
CAS No.:1448702-14-4
Molecular Formula:C₂₇H₄₇NO₄Si₂
Molecular Weight:505.845
Hs Code.:

Synonyms:(2E)-methyl-(4S,5S,6S)-N-benzyl-4,6-bis(tert-butyldimethylsilyloxy)-5,7-iminohept-2-enoate

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Chemical Property of (2E)-methyl-(4S,5S,6S)-N-benzyl-4,6-bis(tert-butyldimethylsilyloxy)-5,7-iminohept-2-enoate

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Technology Process of (2E)-methyl-(4S,5S,6S)-N-benzyl-4,6-bis(tert-butyldimethylsilyloxy)-5,7-iminohept-2-enoate

There total 3 articles about (2E)-methyl-(4S,5S,6S)-N-benzyl-4,6-bis(tert-butyldimethylsilyloxy)-5,7-iminohept-2-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 69739-34-0
t-butyldimethylsiyl triflate

: 1448702-10-0
(2E)-methyl-(4S,5S,6S)-N-benzyl-4,6-dihydroxy-5,7-iminohept-2-enoate

: 1448702-14-4
(2E)-methyl-(4S,5S,6S)-N-benzyl-4,6-bis(tert-butyldimethylsilyloxy)-5,7-iminohept-2-enoate

Guidance literature:: With 2,6-dimethylpyridine; In N,N-dimethyl-formamide; at 20 ℃; for 22h;
DOI:10.1016/j.bmc.2013.03.004

Reference yield:

: 1448702-21-3
C₁₂H₁₅NO₃

: 1448702-14-4
(2E)-methyl-(4S,5S,6S)-N-benzyl-4,6-bis(tert-butyldimethylsilyloxy)-5,7-iminohept-2-enoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydroxide / water; dichloromethane / 0.25 h

1.2: 16 h / 20 °C

2.1: 2,6-dimethylpyridine / N,N-dimethyl-formamide / 22 h / 20 °C

With 2,6-dimethylpyridine; sodium hydroxide; In dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1016/j.bmc.2013.03.004

Reference yield:

: 1338054-44-6
N-benzyl-1,2-O-isopropylidene-3,5-dideoxy-3,5-imino-β-L-lyxofuranose

: 1448702-14-4
(2E)-methyl-(4S,5S,6S)-N-benzyl-4,6-bis(tert-butyldimethylsilyloxy)-5,7-iminohept-2-enoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: trifluoroacetic acid / water / 24 h / 20 °C

2.1: sodium hydroxide / water; dichloromethane / 0.25 h

2.2: 16 h / 20 °C

3.1: 2,6-dimethylpyridine / N,N-dimethyl-formamide / 22 h / 20 °C

With 2,6-dimethylpyridine; trifluoroacetic acid; sodium hydroxide; In dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1016/j.bmc.2013.03.004