cis-PdMe₂(PEt₂Ph)2

Base Information

Chemical Name:cis-PdMe₂(PEt₂Ph)2
CAS No.:77881-04-0
Molecular Formula:C₂₂H₃₆P₂Pd
Molecular Weight:468.895
Hs Code.:

cis-PdMe<sub>2</sub>(PEt<sub>2</sub>Ph)2

Synonyms:cis-PdMe₂(PEt₂Ph)2

Suppliers and Price of cis-PdMe₂(PEt₂Ph)2

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of cis-PdMe₂(PEt₂Ph)2

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of cis-PdMe₂(PEt₂Ph)2

There total 4 articles about cis-PdMe₂(PEt₂Ph)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 77831-30-2
trans-PdMe₂(PEt₂Ph)2

: 77881-04-0
cis-PdMe₂(PEt₂Ph)2

Guidance literature:: With methyllithium; In diethyl ether; under N2 or Ar, to Et2O soln. of Pd complex ether soln. of MeLi added at room temp., stirred for 2 h, hydrolyzed at 0°C; evapd., ppt. washed with Et2O, dried in vac.;
DOI:10.1246/bcsj.54.1868

Reference yield: 85.0%

: 29484-77-3
trans-[Pd(phenyldiethylphosphine)2Cl₂]

: 917-54-4
methyllithium

: 77881-04-0
cis-PdMe₂(PEt₂Ph)2

Guidance literature:: In diethyl ether; byproducts: LiCl; under N2 or Ar, to mixt. of Pd complex and Et2O contg. small amt. of PEt2Ph Et2O soln. of MeLi added at -30°C, stirred at room temp. for2 h; evapd., hydrolyzed at 0°C, recrystd. from Et2O; elem. anal.;
DOI:10.1246/bcsj.54.1868

Reference yield:

: sodium tetrachloropalladate(II)

: 917-54-4
methyllithium

: 1605-53-4
diethyl-phenyl-phosphine

: 83947-24-4
Li⁽¹⁺⁾*Pd(CH₃)3P(C₂H₅)2C₆H₅^(1-)=Li(Pd(CH₃)3P(C₂H₅)2C₆H₅)

: 83947-30-2
dilithium tetramethylpalladate(II)

: 77881-04-0
cis-PdMe₂(PEt₂Ph)2

Guidance literature:: In diethyl ether; byproducts: LiCl; PEt2Ph was added under inert atmosphere to a suspn. of Na2PdCl4 in Et2O, resulting ppt. of PdCl2(PEt2Ph)2 was treated without isolation with anether soln. of MeLi at room temp.; not isolated from the soln.; (1)H NMR spectral data;
DOI:10.1021/om00074a007