O-<1-O-<11-<<(2,4,6-Trimethylbenzyl)oxy>carbonyl>undecyl>-2-O-methyl-sn-glycero-3-phosphoryl>-2',3'-isopropylidene-sn-glycerol

Base Information

Chemical Name:O-<1-O-<11-<<(2,4,6-Trimethylbenzyl)oxy>carbonyl>undecyl>-2-O-methyl-sn-glycero-3-phosphoryl>-2',3'-isopropylidene-sn-glycerol
CAS No.:153959-45-6
Molecular Formula:C₃₂H₅₅O₁₀P
Molecular Weight:630.756
Hs Code.:

Synonyms:O-<1-O-<11-<<(2,4,6-Trimethylbenzyl)oxy>carbonyl>undecyl>-2-O-methyl-sn-glycero-3-phosphoryl>-2',3'-isopropylidene-sn-glycerol

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Chemical Property of O-<1-O-<11-<<(2,4,6-Trimethylbenzyl)oxy>carbonyl>undecyl>-2-O-methyl-sn-glycero-3-phosphoryl>-2',3'-isopropylidene-sn-glycerol

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Technology Process of O-<1-O-<11-<<(2,4,6-Trimethylbenzyl)oxy>carbonyl>undecyl>-2-O-methyl-sn-glycero-3-phosphoryl>-2',3'-isopropylidene-sn-glycerol

There total 9 articles about O-<1-O-<11-<<(2,4,6-Trimethylbenzyl)oxy>carbonyl>undecyl>-2-O-methyl-sn-glycero-3-phosphoryl>-2',3'-isopropylidene-sn-glycerol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.5%

: 153959-43-4
1-O-<11-<<(2,4,6-Trimethylbenzyl)oxy>carbonyl>undecyl>-2-O-methyl-sn-glyceryl o-chlorophenyl 2',3'-isopropylidene-sn-glyceryl phosphate

: 153959-45-6
O-<1-O-<11-<<(2,4,6-Trimethylbenzyl)oxy>carbonyl>undecyl>-2-O-methyl-sn-glycero-3-phosphoryl>-2',3'-isopropylidene-sn-glycerol

Guidance literature:: With 2-pyridinealdoxime; 1,1,3,3-tetramethylguanidine; In tetrahydrofuran; water; for 20h; Ambient temperature;
DOI:10.1021/jo00082a009

Reference yield:

: 505-95-3
12-hydroxydodecanoic acid

: 153959-45-6
O-<1-O-<11-<<(2,4,6-Trimethylbenzyl)oxy>carbonyl>undecyl>-2-O-methyl-sn-glycero-3-phosphoryl>-2',3'-isopropylidene-sn-glycerol

Guidance literature:: Multi-step reaction with 6 steps

1: 84 percent / Et₃N / ethyl acetate / 12 h / Heating

2: 60.6 percent / BF₃*Et₂O / CHCl₃ / Ambient temperature

3: NaH / hexane; tetrahydrofuran / 28 h

4: TBAF / tetrahydrofuran / 0.75 h

5: pyridine / tetrahydrofuran / 4 h

6: 90.5 percent / 2-pyridinealdoxime, tetramethylguanidine / tetrahydrofuran; H₂O / 20 h / Ambient temperature

With pyridine; 2-pyridinealdoxime; 1,1,3,3-tetramethylguanidine; boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; sodium hydride; triethylamine; In tetrahydrofuran; hexane; chloroform; water; ethyl acetate;
DOI:10.1021/jo00082a009

Reference yield:

: 1585-16-6
2-chloromethyl-1,3,5-trimethylbenzene

: 153959-45-6
O-<1-O-<11-<<(2,4,6-Trimethylbenzyl)oxy>carbonyl>undecyl>-2-O-methyl-sn-glycero-3-phosphoryl>-2',3'-isopropylidene-sn-glycerol

Guidance literature:: Multi-step reaction with 6 steps

1: 84 percent / Et₃N / ethyl acetate / 12 h / Heating

2: 60.6 percent / BF₃*Et₂O / CHCl₃ / Ambient temperature

3: NaH / hexane; tetrahydrofuran / 28 h

4: TBAF / tetrahydrofuran / 0.75 h

5: pyridine / tetrahydrofuran / 4 h

6: 90.5 percent / 2-pyridinealdoxime, tetramethylguanidine / tetrahydrofuran; H₂O / 20 h / Ambient temperature

With pyridine; 2-pyridinealdoxime; 1,1,3,3-tetramethylguanidine; boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; sodium hydride; triethylamine; In tetrahydrofuran; hexane; chloroform; water; ethyl acetate;
DOI:10.1021/jo00082a009