benzyl (1E,5E)-7-(methoxycarbonyloxy)-1-phenylhepta-1,5-dien-3-yl(tosylcarbamoyl)carbamate

Base Information

Chemical Name:benzyl (1E,5E)-7-(methoxycarbonyloxy)-1-phenylhepta-1,5-dien-3-yl(tosylcarbamoyl)carbamate
CAS No.:1245904-46-4
Molecular Formula:C₃₁H₃₂N₂O₈S
Molecular Weight:592.67
Hs Code.:

Synonyms:benzyl (1E,5E)-7-(methoxycarbonyloxy)-1-phenylhepta-1,5-dien-3-yl(tosylcarbamoyl)carbamate

Suppliers and Price of benzyl (1E,5E)-7-(methoxycarbonyloxy)-1-phenylhepta-1,5-dien-3-yl(tosylcarbamoyl)carbamate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of benzyl (1E,5E)-7-(methoxycarbonyloxy)-1-phenylhepta-1,5-dien-3-yl(tosylcarbamoyl)carbamate

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of benzyl (1E,5E)-7-(methoxycarbonyloxy)-1-phenylhepta-1,5-dien-3-yl(tosylcarbamoyl)carbamate

There total 1 articles about benzyl (1E,5E)-7-(methoxycarbonyloxy)-1-phenylhepta-1,5-dien-3-yl(tosylcarbamoyl)carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 1245904-41-9
benzyl (1E,5E)-7-(methoxycarbonyloxy)-1-phenylhepta-1,5-dien-3-ylcarbamate

: 4083-64-1
Tosyl isocyanate

: 1245904-46-4
benzyl (1E,5E)-7-(methoxycarbonyloxy)-1-phenylhepta-1,5-dien-3-yl(tosylcarbamoyl)carbamate

Guidance literature:: benzyl (1E,5E)-7-(methoxycarbonyloxy)-1-phenylhepta-1,5-dien-3-ylcarbamate; With n-butyllithium; In diethyl ether; hexane; at -78 ℃; for 0.25h;

Tosyl isocyanate; In diethyl ether; hexane; at -78 ℃; for 1.08333h;
DOI:10.1021/ol101755m

Reference yield: 95.0%

: 1245904-46-4
benzyl (1E,5E)-7-(methoxycarbonyloxy)-1-phenylhepta-1,5-dien-3-yl(tosylcarbamoyl)carbamate

: anti-benzyl 2-oxo-6-styryl-3-tosyl-4-vinyltetrahydropyrimidine-1(2H)-carboxylate

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In dichloromethane; at 20 ℃; for 4h; optical yield given as %de; diastereoselective reaction;
DOI:10.1021/ol101755m

Reference yield:

: 1245904-46-4
benzyl (1E,5E)-7-(methoxycarbonyloxy)-1-phenylhepta-1,5-dien-3-yl(tosylcarbamoyl)carbamate

: anti-benzyl 2-oxo-6-styryl-3-tosyl-4-vinyltetrahydropyrimidine-1(2H)-carboxylate

: syn-benzyl 2-oxo-6-styryl-3-tosyl-4-vinyltetrahydropyrimidine-1(2H)-carboxylate

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 20 ℃; for 3h; optical yield given as %de;
DOI:10.1021/ol101755m