methyl 3,4-di-O-benzoyl-2,6-dideoxyhexopyranoside

Base Information

Chemical Name:methyl 3,4-di-O-benzoyl-2,6-dideoxyhexopyranoside
CAS No.:32469-90-2
Molecular Formula:C21H22 O6
Molecular Weight:370.3958
Hs Code.:
Mol file:32469-90-2.mol

Synonyms:D-ribo-Hexopyranoside,methyl 2,6-dideoxy-, dibenzoate, a- (8CI); NSC 278777

Suppliers and Price of methyl 3,4-di-O-benzoyl-2,6-dideoxyhexopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of methyl 3,4-di-O-benzoyl-2,6-dideoxyhexopyranoside

Chemical Property:

Vapor Pressure:1.5E-09mmHg at 25°C
Boiling Point:484.7°Cat760mmHg
Flash Point:211.1°C
Density:1.23g/cm³

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of methyl 3,4-di-O-benzoyl-2,6-dideoxyhexopyranoside

There total 9 articles about methyl 3,4-di-O-benzoyl-2,6-dideoxyhexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 18933-67-0
methyl 3,4-di-O-benzoyl-6-bromo-2,6-dideoxy-α-D-ribo-hexopyranoside

: 32469-90-2
methyl 3,4-di-O-benzoyl-2,6-dideoxy-α-D-ribohexopyranoside

Guidance literature:: With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In toluene; at 95 ℃; for 24h; Inert atmosphere;
DOI:10.1021/acs.jnatprod.5b01051

Reference yield:

: 98-88-4
benzoyl chloride

: 32469-90-2
methyl 3,4-di-O-benzoyl-2,6-dideoxy-α-D-ribohexopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / 22 h / 0 - 20 °C / Inert atmosphere

2: N-Bromosuccinimide; barium carbonate / tetrachloromethane / 5 h / 90 °C / Inert atmosphere

3: 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride / toluene / 24 h / 95 °C / Inert atmosphere

With pyridine; N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; barium carbonate; In tetrachloromethane; toluene;
DOI:10.1021/acs.jnatprod.5b01051

Reference yield:

: 32469-89-9
methyl 3-O-benzoyl-4,6-O-benzylidene-2-deoxy-α-D-ribohexopyranoside

: 32469-90-2
methyl 3,4-di-O-benzoyl-2,6-dideoxy-α-D-ribohexopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: N-Bromosuccinimide; barium carbonate / tetrachloromethane / 5 h / 90 °C / Inert atmosphere

2: 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride / toluene / 24 h / 95 °C / Inert atmosphere

With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; barium carbonate; In tetrachloromethane; toluene;
DOI:10.1021/acs.jnatprod.5b01051