10,11-Anhydro-5,7-dideoxy-1,2-O-isopropylidene-9-O-(methoxymethyl)-7-C-<<(2-nitrophenyl)seleno>methyl>-β-L-ido-L-ido-undecofuranose

Base Information

Chemical Name:10,11-Anhydro-5,7-dideoxy-1,2-O-isopropylidene-9-O-(methoxymethyl)-7-C-<<(2-nitrophenyl)seleno>methyl>-β-L-ido-L-ido-undecofuranose
CAS No.:170873-34-4
Molecular Formula:C₂₃H₃₃NO₁₁Se
Molecular Weight:578.475
Hs Code.:

Synonyms:10,11-Anhydro-5,7-dideoxy-1,2-O-isopropylidene-9-O-(methoxymethyl)-7-C-<<(2-nitrophenyl)seleno>methyl>-β-L-ido-L-ido-undecofuranose

Suppliers and Price of 10,11-Anhydro-5,7-dideoxy-1,2-O-isopropylidene-9-O-(methoxymethyl)-7-C-<<(2-nitrophenyl)seleno>methyl>-β-L-ido-L-ido-undecofuranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 10,11-Anhydro-5,7-dideoxy-1,2-O-isopropylidene-9-O-(methoxymethyl)-7-C-<<(2-nitrophenyl)seleno>methyl>-β-L-ido-L-ido-undecofuranose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 10,11-Anhydro-5,7-dideoxy-1,2-O-isopropylidene-9-O-(methoxymethyl)-7-C-<<(2-nitrophenyl)seleno>methyl>-β-L-ido-L-ido-undecofuranose

There total 15 articles about 10,11-Anhydro-5,7-dideoxy-1,2-O-isopropylidene-9-O-(methoxymethyl)-7-C-<<(2-nitrophenyl)seleno>methyl>-β-L-ido-L-ido-undecofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 170873-33-3
3-O-(tert-Butyldimethylsilyl)-10-chloro-5,7,10-trideoxy-6,8,11-tri-O-(triethylsilyl)-1,2-O-isopropylidene-9-O-(methoxymethyl)-7-C-<<(2-nitrophenyl)seleno>methyl>-α-D-gluco-L-ido-undecofuranose

: 170873-34-4
10,11-Anhydro-5,7-dideoxy-1,2-O-isopropylidene-9-O-(methoxymethyl)-7-C-<<(2-nitrophenyl)seleno>methyl>-β-L-ido-L-ido-undecofuranose

Guidance literature:: With cesium fluoride; In N,N-dimethyl-formamide; at 20 ℃; for 24h;
DOI:10.1021/jo00123a021

Reference yield:

: 170872-96-5
(+)-1,2-O-Isopropylidene-5-O-(phenoxythiocarbonyl)-α-D-glucurono-6,3-lactone

: 170873-34-4
10,11-Anhydro-5,7-dideoxy-1,2-O-isopropylidene-9-O-(methoxymethyl)-7-C-<<(2-nitrophenyl)seleno>methyl>-β-L-ido-L-ido-undecofuranose

Guidance literature:: Multi-step reaction with 11 steps

1: NaBH₃CN / 2 h / 0 °C

2: 2,6-lutidine / CH₂Cl₂ / 2 h / 0 °C

3: 78 percent / Bu₃SnH, AIBN / toluene / 2 h / 80 °C

4: 88 percent / DIBAH / CH₂Cl₂ / 0.5 h / -65 °C

5: n-BuLi, (Me₃Si)2NH / tetrahydrofuran; hexane / -65 °C

6: 84 percent / MeONa / tetrahydrofuran; methanol / 0.17 h / -20 °C

7: 66 percent / NaBH₄ / methanol / 0.17 h / 0 °C

8: 91 percent / pyridine / 18 h / 20 °C

9: 77 percent / DIBAH / toluene / 0.5 h / -65 °C

10: 76 percent / Bu₃P / tetrahydrofuran / 1 h / 50 °C

11: 78 percent / CsF / dimethylformamide / 24 h / 20 °C

With pyridine; 2,6-dimethylpyridine; sodium tetrahydroborate; n-butyllithium; 2,2'-azobis(isobutyronitrile); tributylphosphine; tri-n-butyl-tin hydride; sodium methylate; diisobutylaluminium hydride; sodium cyanoborohydride; cesium fluoride; 1,1,1,3,3,3-hexamethyl-disilazane; In tetrahydrofuran; methanol; hexane; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1021/jo00123a021

Reference yield:

: 170872-97-6
3-O-(tert-Butyldimethylsilyl)-5-deoxy-1,2-O-isopropylidene-α-D-xylo-hexodialdo-1,4-furanose

: 170873-34-4
10,11-Anhydro-5,7-dideoxy-1,2-O-isopropylidene-9-O-(methoxymethyl)-7-C-<<(2-nitrophenyl)seleno>methyl>-β-L-ido-L-ido-undecofuranose

Guidance literature:: Multi-step reaction with 7 steps

1: n-BuLi, (Me₃Si)2NH / tetrahydrofuran; hexane / -65 °C

2: 84 percent / MeONa / tetrahydrofuran; methanol / 0.17 h / -20 °C

3: 66 percent / NaBH₄ / methanol / 0.17 h / 0 °C

4: 91 percent / pyridine / 18 h / 20 °C

5: 77 percent / DIBAH / toluene / 0.5 h / -65 °C

6: 76 percent / Bu₃P / tetrahydrofuran / 1 h / 50 °C

7: 78 percent / CsF / dimethylformamide / 24 h / 20 °C

With pyridine; sodium tetrahydroborate; n-butyllithium; tributylphosphine; sodium methylate; diisobutylaluminium hydride; cesium fluoride; 1,1,1,3,3,3-hexamethyl-disilazane; In tetrahydrofuran; methanol; hexane; N,N-dimethyl-formamide; toluene;
DOI:10.1021/jo00123a021