4-Benzyloxy-2-formylphenylboronic acid

Base Information

Chemical Name:4-Benzyloxy-2-formylphenylboronic acid
CAS No.:139962-97-3
Molecular Formula:C14H13BO4
Molecular Weight:256.066
Hs Code.:2931900090
European Community (EC) Number:834-789-5
DSSTox Substance ID:DTXSID80396973
Nikkaji Number:J3.224.637K
Wikidata:Q72442278
Mol file:139962-97-3.mol

Synonyms:139962-97-3;4-benzyloxy-2-formylphenylboronic acid;(4-(Benzyloxy)-2-formylphenyl)boronic acid;(4-BENZYLOXY-2-FORMYL)PHENYLBORONIC ACID;(2-formyl-4-phenylmethoxyphenyl)boronic acid;4-benzyloxy-2-formylphenyl boronic acid;4-(benzyloxy)-2-formylphenylboronic acid;MFCD02179486;[4-(benzyloxy)-2-formylphenyl]boronic acid;(4-benzyloxy-2-formyl)phenyl boronic acid;(4-benzyloxy-2-formyl-phenyl)boronic acid;BORONIC ACID, B-[2-FORMYL-4-(PHENYLMETHOXY)PHENYL]-;4-Benzyloxy-2-formylphenyl]boronic acid;(4-(Benzyloxy)-2-formylphenyl)boronicacid;(4-benzyloxy-2-formyl) phenyl boronic acid;4-BENZYLOXY-2-FORMYLBENZENEBORONIC ACID;Boronic acid, [2-formyl-4-(phenylmethoxy)phenyl]-;SCHEMBL1128651;DTXSID80396973;AMY10995;AKOS004116290;AB11241;AC-2396;2-Formyl-4-(benzyloxy)phenylboronic acid;AS-55545;A3018;B5257;CS-0156177;FT-0600751;N12223;J-514497;(4-benzyloxy-2-formyl)phenylboronic acid, AldrichCPR;BRD-K95105641-001-01-1;5-O-(4,4-DIMETHOXYTRITYL)-THYMIDINE-3-O-SUCCINICACID;4-Benzyloxy-2-formylphenylboronic Acid (contains varying amounts of Anhydride)

Suppliers and Price of 4-Benzyloxy-2-formylphenylboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(4-Benzyloxy-2-formyl)phenylboronicacid
500mg
$ 95.00

TCI Chemical
4-Benzyloxy-2-formylphenylboronic Acid (contains varying amounts of Anhydride)
200mg
$ 67.00

TCI Chemical
4-Benzyloxy-2-formylphenylboronic Acid (contains varying amounts of Anhydride)
1g
$ 231.00

SynQuest Laboratories
4-(Benzyloxy)-2-formylbenzeneboronic acid
1 g
$ 242.00

SynQuest Laboratories
4-(Benzyloxy)-2-formylbenzeneboronic acid
5 g
$ 536.00

Crysdot
(4-(Benzyloxy)-2-formylphenyl)boronicacid 97%
25g
$ 626.00

Chem-Impex
4-Benzyloxy-2-formylphenylboronicacid,98-105%(Assaybytitration) 98-105%(Assaybytitration)
1G
$ 266.56

Chem-Impex
4-Benzyloxy-2-formylphenylboronicacid,98-105%(Assaybytitration) 98-105%(Assaybytitration)
200MG
$ 69.44

Biosynth Carbosynth
(4-Benzyloxy-2-formyl)phenylboronicacid
50 mg
$ 107.00

Biosynth Carbosynth
(4-Benzyloxy-2-formyl)phenylboronicacid
25 mg
$ 62.00

Total 51 raw suppliers

Chemical Property of 4-Benzyloxy-2-formylphenylboronic acid

Chemical Property:

Vapor Pressure:2E-10mmHg at 25°C
Refractive Index:1.599
Boiling Point:490.199 °C at 760 mmHg
Flash Point:250.264 °C
PSA：66.76000
Density:1.263 g/cm³
LogP:0.75790
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:5
Exact Mass:256.0906891
Heavy Atom Count:19
Complexity:279

Purity/Quality:

99% ^*data from raw suppliers

(4-Benzyloxy-2-formyl)phenylboronicacid ^*data from reagent suppliers

Safty Information:

Pictogram(s): C
Hazard Codes:C,Xi
Statements: 36/37/38-43-36
Safety Statements: 26-36/37/39-36/37

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C1=C(C=C(C=C1)OCC2=CC=CC=C2)C=O)(O)O
Uses suzuki reaction

Technology Process of 4-Benzyloxy-2-formylphenylboronic acid

There total 7 articles about 4-Benzyloxy-2-formylphenylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 1195-66-0
2-methoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 139962-96-2
5-Benzyloxy-2-bromobenzaldehyde diethyl acetal

: 139962-97-3
3-Benzyloxy-6-boronobenzaldehyde diethyl acetal

Guidance literature:: 5-Benzyloxy-2-bromobenzaldehyde diethyl acetal; With isopropyl magnesium chloride; In tetrahydrofuran; at -20 - 20 ℃; Inert atmosphere;

2-methoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; With hydrogenchloride; In tetrahydrofuran; at 0 - 80 ℃; pH=<= 3;

Reference yield: 52.0%

: (4-(benzyloxy)-2-formylphenyl)boronic acid pinacol ester

: 139962-97-3
3-Benzyloxy-6-boronobenzaldehyde diethyl acetal

Guidance literature:: C₂₀H₂₃BO₄; With sodium periodate; In tetrahydrofuran; water; at 20 ℃; for 0.333333h;

With hydrogenchloride; In water; at 20 ℃; for 2h;
DOI:10.1039/d1cc03026d

Reference yield:

: 85604-06-4
5-(benzyloxy)-2-bromobenzaldehyde

: 139962-97-3
3-Benzyloxy-6-boronobenzaldehyde diethyl acetal

Guidance literature:: Multi-step reaction with 2 steps

1.1: ammonium chloride / ethanol / 5 h / Reflux

2.1: isopropyl magnesium chloride / tetrahydrofuran / -20 - 20 °C / Inert atmosphere

2.2: 0 - 80 °C / pH <= 3

With ammonium chloride; isopropyl magnesium chloride; In tetrahydrofuran; ethanol;