Copper;dichloride;hydrate

Base Information

• Chemical Name: Copper;dichloride;hydrate
• CAS No.: 10125-13-0
• Molecular Formula: Cl₂CuH₄O₂
• Molecular Weight: 170.483
• Hs Code.: 28273990
• Mol file: 10125-13-0.mol

Synonyms:

Chemical Property of Copper;dichloride;hydrate

Chemical Property:

• Appearance/Colour: moist blue crystals.
• Melting Point: 100 °C (dec.)(lit.)
• Boiling Point: 100 °C at 760 mmHg
• PSA: 18.46000
• Density: 2.54 g/cm³
• LogP: 1.24790
• Storage Temp.: Store at RT.
• Sensitive.: Air Sensitive & Hygroscopic
• Solubility.: 757g/l
• Water Solubility.: 1150 g/L
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 150.877867
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Copper(II) chloride dihydrate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn,N
• Hazard Codes: Xn,N
• Statements: 22-36/37/38-50/53-50-41-38-21/22
• Safety Statements: 26-60-61-36-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: O.[Cl-].[Cl-].[Cu+2]
• Description: Copper (II) chloride dihydrate is used in the preparation of copper oxychloride and as a catalyst in many organic chlorination reactions such as vinyl chloride and 1,2-dichloroethane. Copper chloride dihydrate may be also used as catalyst to cleave tetrahydropyranyl (THP) ethers and t-butyldimethylsilyl (TBDMS) ethers and to chemoselectively hydrolyze semicarbazones to carbonyl compounds. Solution of copper (II) chloride is used for plating on aluminum and for tinting germanium and tin.
• Uses: Copper(II) chloride is used as a mordant in dyeing and printing of fabrics; as an ingredient of isomerization and cracking catalysts; and as a desulfurizing and deodorizing agent in petroleum industry. Other important applications are in copper plating of aluminum; preparation of copper standard solutions; test for molybdenum; in tinting-baths for iron and tin; in pigments for ceramics and glasses; as a fixer and desensitizer reagent in photography; in mercury extraction from ores; in laundry-marking and invisible inks; and in manufacture of several copper salts. Supplement (trace mineral). Copper(II) chloride (CuCl2) or cupric chloride, is a brownish-yellow hygroscopic powder, or it may be formed as green deliquescent crystals. It is used in the dyeing and printing of textiles, as a disinfectant, as red pigment in the glass and ceramic industries, and for green-colored pyrotechnics, wood preservative, fungicide, deodorizer, water purification, feed additive, and electroplating baths. Copper(II) chloride dihydrate has been used as a positive control in dispersion of zebrafish embryo. It has also been used for the preparation of trace metals mixture.

Refernces

Trifluoromethylated enaminones and their explorative coordination chemistry with Cu(ii): Synthesis, redox properties and structural characterization of the complexes

10.1039/b805071f

The research focuses on the synthesis, redox properties, and coordination chemistry of three novel trifluoromethylated enaminones (L1H–L3H) with copper(II). The purpose of this study is to explore the potential of these ligands to form coordination complexes with copper(II) and to investigate their redox behavior, which could have applications in catalysis, magnetism, and materials science. The enaminone ligands were synthesized through a two-step process involving trifluoroacetylation of ethyl vinyl ether followed by an O–N exchange reaction with various amines. The copper(II) complexes were prepared by reacting the ligands with CuCl2·2H2O in methanol. The structures of the complexes were determined by single-crystal X-ray diffraction, revealing monomeric and dimeric forms. Electrochemical studies showed that the reduction processes of the complexes were different in dichloromethane and N,N-dimethylformamide, with copper(II) being directly reduced to copper(0) in the former and a copper(I) intermediate being more stable in the latter. The conclusions suggest that these enaminone ligands have potential for further development into heteromultinuclear complexes with interesting electro-magnetic properties.

Enantioselective synthesis of alkyne-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution reactions with (i -Bu)₂(Alkynyl)aluminum reagents

10.1021/ja2010829

The research focuses on the development of a catalytic enantioselective method for the synthesis of alkyne-substituted all-carbon quaternary stereogenic centers. The experiments involve the addition of alkynylaluminum reagents to variously substituted allylic phosphates, facilitated by NHC-Cu complexes derived from air-stable CuCl2·2H2O. The Al-based reagents are prepared by treating terminal alkynes with diisobutylaluminum hydride in the presence of Et3N. The reactions yield 1,4-enynes with high enantioselectivity (up to >99:1 enantiomeric ratio) and good yields (up to 98%). The study also demonstrates the utility of these enantiomerically enriched products in chemical synthesis through Au-catalyzed cyclizations. Analytical techniques such as 1H NMR, HPLC, and X-ray crystallography were used to characterize the products and assess the enantiomeric ratios and yields.