(S)-N-(1-(diphenylphosphino)-3,3-dimethylbutan-2-yl)-3,5-dinitrobenzamide

Base Information

• Chemical Name: (S)-N-(1-(diphenylphosphino)-3,3-dimethylbutan-2-yl)-3,5-dinitrobenzamide
• CAS No.: 1239020-06-4
• Molecular Formula: C₂₅H₂₆N₃O₅P
• Molecular Weight: 479.472
• Mol file: 1239020-06-4.mol

Synonyms:(S)-N-(1-(diphenylphosphino)-3,3-dimethylbutan-2-yl)-3,5-dinitrobenzamide

Chemical Property of (S)-N-(1-(diphenylphosphino)-3,3-dimethylbutan-2-yl)-3,5-dinitrobenzamide

Chemical Property:

Purity/Quality:

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Technology Process of (S)-N-(1-(diphenylphosphino)-3,3-dimethylbutan-2-yl)-3,5-dinitrobenzamide

There total 1 articles about (S)-N-(1-(diphenylphosphino)-3,3-dimethylbutan-2-yl)-3,5-dinitrobenzamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

3,5-dinitrobenzoic acid (99-34-3) + (S)‐1‐(diphenylphosphino)‐3,3‐dimethylbutan‐2‐amine (286454-86-2,1366384-12-4) → (S)-N-(1-(diphenylphosphino)-3,3-dimethylbutan-2-yl)-3,5-dinitrobenzamide (1239020-06-4)

Guidance literature:

With (benzotriazo-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate; triethylamine; In tetrahydrofuran; at 0 - 20 ℃;

DOI:10.1002/anie.201000446

Reference yield: 88.0%

(S)-N-(1-(diphenylphosphino)-3,3-dimethylbutan-2-yl)-3,5-dinitrobenzamide (1239020-06-4) + benzyl bromide (100-39-0) → (S)-benzyl(2-(3,5-dinitrobenzamido)-3,3-dimethylbutyl)diphenylphosphonium bromide

Guidance literature:

In toluene; at 110 ℃; for 8h;

DOI:10.1016/j.tet.2015.02.001

upstream raw materials:

3,5-dinitrobenzoic acid

(S)‐1‐(diphenylphosphino)‐3,3‐dimethylbutan‐2‐amine