C₇₁H₁₀₀O₉SSi₃

Base Information

Chemical Name:C₇₁H₁₀₀O₉SSi₃
CAS No.:1261152-34-4
Molecular Formula:C₇₁H₁₀₀O₉SSi₃
Molecular Weight:1213.89
Hs Code.:

C<sub>71</sub>H<sub>100</sub>O<sub>9</sub>SSi<sub>3</sub>

Synonyms:C₇₁H₁₀₀O₉SSi₃

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Chemical Property of C₇₁H₁₀₀O₉SSi₃

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Technology Process of C₇₁H₁₀₀O₉SSi₃

There total 30 articles about C₇₁H₁₀₀O₉SSi₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

: 1261152-57-1
C₆₉H₉₆O₁₀Si₃

: 75-08-1
ethanethiol

: 1261152-58-2
C₇₁H₁₀₀O₉SSi₃

: 1261152-34-4
C₇₁H₁₀₀O₉SSi₃

Guidance literature:: With zinc trifluoromethanesulfonate; In dichloromethane; at 25 ℃; for 16h; optical yield given as %de; Inert atmosphere;
DOI:10.1021/ja109533y

Reference yield:

: C₃₉H₆₄O₆Si₃

: 1261152-34-4
C₇₁H₁₀₀O₉SSi₃

Guidance literature:: Multi-step reaction with 20 steps

1.1: diisobutylaluminium hydride / dichloromethane / 1 h / -78 °C / Inert atmosphere

1.2: 16 h / 25 °C / Inert atmosphere

2.1: titanium(IV) isopropylate; diethyl (2S,3S)-tartrate / dichloromethane / 1 h / -25 °C / Inert atmosphere; Molecular sieve

2.2: 17 h / -20 °C / Inert atmosphere; Molecular sieve

3.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; triethylamine / dichloromethane / 0 - 25 °C / Inert atmosphere

4.1: dichloromethane / 14 h / 20 °C / Inert atmosphere

5.1: tetrabutyl ammonium fluoride / dichloromethane / 0.33 h / 0 °C / Inert atmosphere

6.1: pyridinium p-toluenesulfonate / dichloromethane / 25 - 40 °C / Inert atmosphere

7.1: lanthanum(lll) triflate / toluene / 6 h / 25 °C / Inert atmosphere

8.1: sodium tetrahydroborate; nickel (II) chloride hexahydrate / ethanol / 0 °C / Inert atmosphere

9.1: lithium aluminium tetrahydride / tetrahydrofuran; diethyl ether / 0.5 h / 25 °C / Inert atmosphere

10.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; triethylamine / dichloromethane / 0 - 25 °C / Inert atmosphere

11.1: sodium hexamethyldisilazane / tetrahydrofuran; toluene / 0.17 h / 0 °C / Inert atmosphere

11.2: 0.33 h / 0 °C / Inert atmosphere

12.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 3 h / 0 °C / Inert atmosphere

13.1: dmap; 2-methyl-6-nitrobenzoic anhydride; triethylamine / toluene / 0.33 h / 25 °C / Inert atmosphere; Molecular sieve

13.2: 13 h / 25 °C / Inert atmosphere; Molecular sieve

14.1: p-toluenesulfonic acid monohydrate / methanol; dichloromethane / 0.67 h / 0 °C / Inert atmosphere

15.1: N,N,N,N,-tetramethylethylenediamine; titanium tetrachloride / tetrahydrofuran; dichloromethane / 0 - 25 °C / Inert atmosphere

15.2: 0.67 h / 25 °C / Inert atmosphere

16.1: 2,6-dimethylpyridine / dichloromethane / 1 h / 0 °C / Inert atmosphere

17.1: bis(cyclohexanyl)borane / tetrahydrofuran / 6 h / 25 °C / Inert atmosphere

17.2: 20 h / 0 °C / Inert atmosphere

18.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0 - 25 °C / Inert atmosphere

19.1: p-toluenesulfonic acid monohydrate / methanol; dichloromethane / 0.5 h / 0 °C / Inert atmosphere

20.1: zinc trifluoromethanesulfonate / dichloromethane / 16 h / 25 °C / Inert atmosphere

With 2,6-dimethylpyridine; titanium(IV) isopropylate; dmap; sodium tetrahydroborate; lithium aluminium tetrahydride; nickel (II) chloride hexahydrate; diethyl (2S,3S)-tartrate; N,N,N,N,-tetramethylethylenediamine; bis(cyclohexanyl)borane; 2-methyl-6-nitrobenzoic anhydride; p-toluenesulfonic acid monohydrate; tetrabutyl ammonium fluoride; sodium hexamethyldisilazane; sulfur trioxide pyridine complex; pyridinium p-toluenesulfonate; titanium tetrachloride; zinc trifluoromethanesulfonate; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; dimethyl sulfoxide; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lanthanum(lll) triflate; In tetrahydrofuran; methanol; diethyl ether; ethanol; dichloromethane; toluene; 2.1: Sharpless epoxidation / 2.2: Sharpless epoxidation / 3.1: Parikh-Doering oxidation / 4.1: Wittig reaction / 10.1: Parikh-Doering oxidation / 11.1: Wittig reaction / 11.2: Wittig reaction / 17.1: Hydroboration reaction;
DOI:10.1021/ja109533y

Reference yield:

: C₃₇H₆₀O₆Si₃

: 1261152-34-4
C₇₁H₁₀₀O₉SSi₃

Guidance literature:: Multi-step reaction with 17 steps

1.1: dichloromethane / 14 h / 20 °C / Inert atmosphere

2.1: tetrabutyl ammonium fluoride / dichloromethane / 0.33 h / 0 °C / Inert atmosphere

3.1: pyridinium p-toluenesulfonate / dichloromethane / 25 - 40 °C / Inert atmosphere

4.1: lanthanum(lll) triflate / toluene / 6 h / 25 °C / Inert atmosphere

5.1: sodium tetrahydroborate; nickel (II) chloride hexahydrate / ethanol / 0 °C / Inert atmosphere

6.1: lithium aluminium tetrahydride / tetrahydrofuran; diethyl ether / 0.5 h / 25 °C / Inert atmosphere

7.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; triethylamine / dichloromethane / 0 - 25 °C / Inert atmosphere

8.1: sodium hexamethyldisilazane / tetrahydrofuran; toluene / 0.17 h / 0 °C / Inert atmosphere

8.2: 0.33 h / 0 °C / Inert atmosphere

9.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 3 h / 0 °C / Inert atmosphere

10.1: dmap; 2-methyl-6-nitrobenzoic anhydride; triethylamine / toluene / 0.33 h / 25 °C / Inert atmosphere; Molecular sieve

10.2: 13 h / 25 °C / Inert atmosphere; Molecular sieve

11.1: p-toluenesulfonic acid monohydrate / methanol; dichloromethane / 0.67 h / 0 °C / Inert atmosphere

12.1: N,N,N,N,-tetramethylethylenediamine; titanium tetrachloride / tetrahydrofuran; dichloromethane / 0 - 25 °C / Inert atmosphere

12.2: 0.67 h / 25 °C / Inert atmosphere

13.1: 2,6-dimethylpyridine / dichloromethane / 1 h / 0 °C / Inert atmosphere

14.1: bis(cyclohexanyl)borane / tetrahydrofuran / 6 h / 25 °C / Inert atmosphere

14.2: 20 h / 0 °C / Inert atmosphere

15.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0 - 25 °C / Inert atmosphere

16.1: p-toluenesulfonic acid monohydrate / methanol; dichloromethane / 0.5 h / 0 °C / Inert atmosphere

17.1: zinc trifluoromethanesulfonate / dichloromethane / 16 h / 25 °C / Inert atmosphere

With 2,6-dimethylpyridine; dmap; sodium tetrahydroborate; lithium aluminium tetrahydride; nickel (II) chloride hexahydrate; N,N,N,N,-tetramethylethylenediamine; bis(cyclohexanyl)borane; 2-methyl-6-nitrobenzoic anhydride; p-toluenesulfonic acid monohydrate; tetrabutyl ammonium fluoride; sodium hexamethyldisilazane; sulfur trioxide pyridine complex; pyridinium p-toluenesulfonate; titanium tetrachloride; zinc trifluoromethanesulfonate; sodium hydrogencarbonate; Dess-Martin periodane; dimethyl sulfoxide; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lanthanum(lll) triflate; In tetrahydrofuran; methanol; diethyl ether; ethanol; dichloromethane; toluene; 1.1: Wittig reaction / 7.1: Parikh-Doering oxidation / 8.1: Wittig reaction / 8.2: Wittig reaction / 14.1: Hydroboration reaction;
DOI:10.1021/ja109533y