2,7,12-tris<2-(4-hydroxymethyl-2-methoxyphenoxy)ethoxy>-3,8,13-trimetoxy-10,15-dihydro-5H-tribenzocyclononene

Base Information

• Chemical Name: 2,7,12-tris<2-(4-hydroxymethyl-2-methoxyphenoxy)ethoxy>-3,8,13-trimetoxy-10,15-dihydro-5H-tribenzocyclononene
• CAS No.: 98757-25-6
• Molecular Formula: C₅₁H₅₄O₁₂
• Molecular Weight: 858.983
• Mol file: 98757-25-6.mol

Synonyms:2,7,12-tris<2-(4-hydroxymethyl-2-methoxyphenoxy)ethoxy>-3,8,13-trimetoxy-10,15-dihydro-5H-tribenzocyclononene

Chemical Property of 2,7,12-tris<2-(4-hydroxymethyl-2-methoxyphenoxy)ethoxy>-3,8,13-trimetoxy-10,15-dihydro-5H-tribenzocyclononene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,7,12-tris<2-(4-hydroxymethyl-2-methoxyphenoxy)ethoxy>-3,8,13-trimetoxy-10,15-dihydro-5H-tribenzocyclononene

There total 2 articles about 2,7,12-tris<2-(4-hydroxymethyl-2-methoxyphenoxy)ethoxy>-3,8,13-trimetoxy-10,15-dihydro-5H-tribenzocyclononene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

[3-methyloxy-4-(2-iodoethoxy)phenyl]methanol (81329-97-7) + P-(-)-(C3)-cyclotriphenolene (89255-53-8) → 2,7,12-tris<2-(4-hydroxymethyl-2-methoxyphenoxy)ethoxy>-3,8,13-trimetoxy-10,15-dihydro-5H-tribenzocyclononene (98757-25-6)

Guidance literature:

With sodium hydroxide; In N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl-formamide; for 3h; Ambient temperature;

DOI:10.1021/ja00310a041

Reference yield:

4-hydroxymethyl-2-methoxyphenol (498-00-0) → 2,7,12-tris<2-(4-hydroxymethyl-2-methoxyphenoxy)ethoxy>-3,8,13-trimetoxy-10,15-dihydro-5H-tribenzocyclononene (98757-25-6)

Guidance literature:

Multi-step reaction with 3 steps

1: 26 percent / aq. 12 N sodium hydroxide / ethanol / 5 h / Heating

2: 23 percent / sodium iodide / acetone / 8 h / Heating

3: 89 percent / 25 percent aq. NaOH / dimethylformamide; hexamethylphosphoric acid triamide / 3 h / Ambient temperature

With sodium hydroxide; sodium iodide; In N,N,N,N,N,N-hexamethylphosphoric triamide; ethanol; N,N-dimethyl-formamide; acetone;

DOI:10.1021/ja00310a041

upstream raw materials:

[3-methyloxy-4-(2-iodoethoxy)phenyl]methanol

P-(-)-(C₃)-cyclotriphenolene

4-hydroxymethyl-2-methoxyphenol