5'-(4'-(1-(4-butylphenyl)-1H-phenanthro[9,10-d]imidazol-2-yl)biphenyl-4-yl)-2,2'-bithiophene-5-carbaldehyde

Base Information

Chemical Name:5'-(4'-(1-(4-butylphenyl)-1H-phenanthro[9,10-d]imidazol-2-yl)biphenyl-4-yl)-2,2'-bithiophene-5-carbaldehyde
CAS No.:1384124-42-8
Molecular Formula:C₄₆H₃₄N₂OS₂
Molecular Weight:694.921
Hs Code.:

Synonyms:5'-(4'-(1-(4-butylphenyl)-1H-phenanthro[9,10-d]imidazol-2-yl)biphenyl-4-yl)-2,2'-bithiophene-5-carbaldehyde

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Chemical Property of 5'-(4'-(1-(4-butylphenyl)-1H-phenanthro[9,10-d]imidazol-2-yl)biphenyl-4-yl)-2,2'-bithiophene-5-carbaldehyde

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Technology Process of 5'-(4'-(1-(4-butylphenyl)-1H-phenanthro[9,10-d]imidazol-2-yl)biphenyl-4-yl)-2,2'-bithiophene-5-carbaldehyde

There total 5 articles about 5'-(4'-(1-(4-butylphenyl)-1H-phenanthro[9,10-d]imidazol-2-yl)biphenyl-4-yl)-2,2'-bithiophene-5-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 1359093-60-9
5'-(4-bromophenyl)-[2,2']bithiophenyl-5-carbaldehyde

: 1384124-32-6
4-(1-(4-butylphenyl)-1H-phenanthro[9,10-d]imidazol-2-yl)phenylboronic acid

: 1384124-42-8
5'-(4'-(1-(4-butylphenyl)-1H-phenanthro[9,10-d]imidazol-2-yl)biphenyl-4-yl)-2,2'-bithiophene-5-carbaldehyde

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In tetrahydrofuran; methanol;
DOI:10.1016/j.tet.2012.04.074

Reference yield:

: 1160930-69-7
5-(4-bromophenyl)-[2,2']bithiophene

: 1384124-42-8
5'-(4'-(1-(4-butylphenyl)-1H-phenanthro[9,10-d]imidazol-2-yl)biphenyl-4-yl)-2,2'-bithiophene-5-carbaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: trichlorophosphate

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / tetrahydrofuran; methanol

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; trichlorophosphate; In tetrahydrofuran; methanol; 2: Suzuki coupling;
DOI:10.1016/j.tet.2012.04.074

Reference yield:

: 1122-91-4
4-bromo-benzaldehyde

: 1384124-42-8
5'-(4'-(1-(4-butylphenyl)-1H-phenanthro[9,10-d]imidazol-2-yl)biphenyl-4-yl)-2,2'-bithiophene-5-carbaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1.1: ammonium acetate; acetic acid / 3 h / Reflux

2.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere

2.2: -78 - 20 °C / Inert atmosphere

2.3: 3 h

3.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / tetrahydrofuran; methanol

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; ammonium acetate; potassium carbonate; acetic acid; In tetrahydrofuran; methanol; hexane; 3.1: Suzuki coupling;
DOI:10.1016/j.tet.2012.04.074