(C₆H₄OP(cyclohexyl)2)2

Base Information

• Chemical Name: (C₆H₄OP(cyclohexyl)2)2
• CAS No.: 872217-45-3
• Molecular Formula: C₃₆H₅₂O₂P₂
• Molecular Weight: 578.755
• Mol file: 872217-45-3.mol

Synonyms:(C₆H₄OP(cyclohexyl)2)2

Chemical Property of (C₆H₄OP(cyclohexyl)2)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₆H₄OP(cyclohexyl)2)2

There total 1 articles about (C₆H₄OP(cyclohexyl)2)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

2,2'-dihydroxybiphenyl (1806-29-7) + chlorodicyclohexylphosphane (16523-54-9) → (C6H4OP(cyclohexyl)2)2 (872217-45-3)

Guidance literature:

With triethylamine; In acetonitrile; at 60 ℃;

DOI:10.1016/j.jorganchem.2005.04.048

Reference yield: 67.0%

(C6H4OP(cyclohexyl)2)2 (872217-45-3) + dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) → cis-[PtCl2(C6H4OP(cyclohexyl)2)2] (872217-47-5)

Guidance literature:

In dichloromethane; (Ar); using Schlenk techniques; addn. of soln. of (C6H4OP(C6H11)2)2 in CH2Cl2 to suspn. of (COD)PtCl2 in CH2Cl2; stirring overnight; removal of solvent in vac., washing with pentane and drying in vac., elem. anal.;

DOI:10.1016/j.jorganchem.2005.04.048

Reference yield:

(C6H4OP(cyclohexyl)2)2 (872217-45-3) + chlorobis(cyclooctene)rhodium(I) dimer → [(biphenyl(OPCy2)2)Rh(μ-chloro)]2 (1020188-47-9)

Guidance literature:

In dichloromethane; (Ar); using Schlenk techniques; dissolving of biphenyl(OPCy)2)2 (1 equiv.) and (Rh(COE)2Cl)2 (1 equiv.) in CH2Cl2; stirring at room temp. overnight; removal of solvent in vac., dissolving in toluene, removal of toluene invac.; washing with pentane; drying in vac., elem. anal.;

DOI:10.1016/j.jorganchem.2007.09.035

upstream raw materials:

2,2'-dihydroxybiphenyl

chlorodicyclohexylphosphane

Downstream raw materials:

cis-[PtCl₂(C₆H₄OP(cyclohexyl)2)2]

[(biphenyl(OPCy2)2)Rh(μ-chloro)]2

cis-[PtEt₂(C₆H₄OP(cyclohexyl)2)2]

Refernces