(1H)-2-thioxo-1-pyridyl 3-acetoxy-3-(2,2-diphenylcyclopropyl)-2-methoxy-2-methylpropionata

Base Information

Chemical Name:(1H)-2-thioxo-1-pyridyl 3-acetoxy-3-(2,2-diphenylcyclopropyl)-2-methoxy-2-methylpropionata
CAS No.:679417-95-9
Molecular Formula:C₂₇H₂₇NO₅S
Molecular Weight:477.581
Hs Code.:

Synonyms:(1H)-2-thioxo-1-pyridyl 3-acetoxy-3-(2,2-diphenylcyclopropyl)-2-methoxy-2-methylpropionata

Suppliers and Price of (1H)-2-thioxo-1-pyridyl 3-acetoxy-3-(2,2-diphenylcyclopropyl)-2-methoxy-2-methylpropionata

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1H)-2-thioxo-1-pyridyl 3-acetoxy-3-(2,2-diphenylcyclopropyl)-2-methoxy-2-methylpropionata

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of (1H)-2-thioxo-1-pyridyl 3-acetoxy-3-(2,2-diphenylcyclopropyl)-2-methoxy-2-methylpropionata

There total 4 articles about (1H)-2-thioxo-1-pyridyl 3-acetoxy-3-(2,2-diphenylcyclopropyl)-2-methoxy-2-methylpropionata which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 679417-87-9
3-(diethylphosphatoxy)-3-(2,2-diphenylcyclopropyl)-2-methoxy-2-methylpropionic acid

: 3696-28-4
2,2'-dipyridyl disulfide bis-N-oxide

: 679417-95-9
(1H)-2-thioxo-1-pyridyl 3-acetoxy-3-(2,2-diphenylcyclopropyl)-2-methoxy-2-methylpropionata

Guidance literature:: With tributylphosphine; In dichloromethane; at 0 - 20 ℃;
DOI:10.1021/jo0357972

Reference yield:

: 3-(2,2-diphenyl-cyclopropyl)-3-hydroxy-2-methoxy-2-methyl-propionic acid 2,4-dimethoxy-benzyl ester

: 679417-95-9
(1H)-2-thioxo-1-pyridyl 3-acetoxy-3-(2,2-diphenylcyclopropyl)-2-methoxy-2-methylpropionata

Guidance literature:: Multi-step reaction with 3 steps

1: tetrahydrofuran; hexane / -78 - 20 °C

2: 50 percent / ceric ammonium nitrate / acetonitrile; H₂O / 1 h / 20 °C

3: 68 percent / Bu₃P / CH₂Cl₂ / 0 - 20 °C

With ammonium cerium(IV) nitrate; tributylphosphine; In tetrahydrofuran; hexane; dichloromethane; water; acetonitrile;
DOI:10.1021/jo0357972

Reference yield:

: 679417-86-8
2,4-dimethoxybenzyl 3-(diethylphosphatoxy)-3-(2,2-diphenylcyclopropyl)-2-methoxy-2-methylpropionate

: 679417-95-9
(1H)-2-thioxo-1-pyridyl 3-acetoxy-3-(2,2-diphenylcyclopropyl)-2-methoxy-2-methylpropionata

Guidance literature:: Multi-step reaction with 2 steps

1: 50 percent / ceric ammonium nitrate / acetonitrile; H₂O / 1 h / 20 °C

2: 68 percent / Bu₃P / CH₂Cl₂ / 0 - 20 °C

With ammonium cerium(IV) nitrate; tributylphosphine; In dichloromethane; water; acetonitrile;
DOI:10.1021/jo0357972