2-Bromoanthracene

Base Information

• Chemical Name: 2-Bromoanthracene
• CAS No.: 7321-27-9
• Molecular Formula: C14H9Br
• Molecular Weight: 257.129
• Hs Code.: 29039990
• Mol file: 7321-27-9.mol

Synonyms:2-BROMOANTHRACENE;2-BroMoantharacene;Anthracene, 2-broMo-

Chemical Property of 2-Bromoanthracene

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Melting Point: 220 °C
• Refractive Index: 1.733
• Boiling Point: 389.679 °C at 760 mmHg
• Flash Point: 190.306 °C
• PSA: 0.00000
• Density: 1.479 g/cm³
• LogP: 4.75550
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility.: Chloroform (Slightly), DMSO (Sparingly), Methanol (Very Slightly)

Purity/Quality:

99.3% ^*data from raw suppliers

2-Bromoanthracene ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Bromoanthracene

There total 3 articles about 2-Bromoanthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.02%

2-bromoanthracene-9,10-dione (572-83-8) → 2-bromoanthracene (7321-27-9)

Guidance literature:

2-bromoanthracene-9,10-dione; With potassium borohydride; diethylene glycol dimethyl ether; at 105 ℃; for 0.5h;

With aluminum (III) chloride; at 30 - 110 ℃; for 0.333333h; Concentration; Temperature;

Reference yield:

2-bromoanthracene-9,10-dione (572-83-8) + aluminum tri-sec-butoxide (2269-22-9) → 2-bromoanthracene (7321-27-9)

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; cyclohexanol;

Reference yield:

2-bromoanthracene-9,10-dione (572-83-8) → C14H11Br + 2-bromoanthracene (7321-27-9)

Guidance literature:

With acetic acid; aluminium; indium(III) chloride; In ethanol; water; at 90 ℃; for 11h;

DOI:10.1016/j.tet.2007.03.113

upstream raw materials:

2-bromoanthracene-9,10-dione

aluminum tri-sec-butoxide

Downstream raw materials:

2-anthryldiphenylphosphine

2-(t-butyl)anthracene

9,10-dibromo-2-phenylanthracene

Refernces

• 1、 Kondo, Shin-ichi,Osawa, Kohei,Tagaya, Hideyuki. "Naked eye detection of anions by 2,2¤-bianthracene derivative bearing urea groups in various organic solvents". supporting information. p. 290 - 294. Retrieved 2020/04/10.
• 2、 -. "Preparation method of 2-bromoanthracene". Paragraph 0031; 0032; 0033; 0034; 0035; 0036; 0037-0042. . Retrieved 2017/08/30.