2-P-TERPHENYLBORONIC ACID

Base Information

Chemical Name:2-P-TERPHENYLBORONIC ACID
CAS No.:663954-31-2
Molecular Formula:C18H15BO2
Molecular Weight:274.127
Hs Code.:2931900090
Mol file:663954-31-2.mol

Synonyms:Boronicacid, [1,1':4',1''-terphenyl]-2-yl- (9CI);

Suppliers and Price of 2-P-TERPHENYLBORONIC ACID

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2-p-TerphenylboronicAcid
50mg
$ 60.00

TRC
2-p-TerphenylboronicAcid
10mg
$ 45.00

TCI Chemical
2-p-Terphenylboronic Acid (contains varying amounts of Anhydride)
1g
$ 141.00

Matrix Scientific
1,1':4',1''-Terphenyl-2-boronic acid 97%
1g
$ 331.00

Crysdot
2-P-terphenylboronicacid 97%
1g
$ 108.00

Crysdot
2-P-terphenylboronicacid 97%
5g
$ 324.00

American Custom Chemicals Corporation
2-(BIPHENYL) PHENYLBORONIC ACID 95.00%
1G
$ 780.15

Alichem
2-P-terphenylboronicacid
5g
$ 833.04

Alichem
2-P-terphenylboronicacid
1g
$ 269.67

AK Scientific
2-p-Terphenylboronicacid
1g
$ 239.00

Total 32 raw suppliers

Chemical Property of 2-P-TERPHENYLBORONIC ACID

Chemical Property:

Boiling Point:522.595 °C at 760 mmHg
PKA:8.55±0.58(Predicted)
Flash Point:269.856 °C
PSA：40.46000
Density:1.211 g/cm³
LogP:2.70040
Storage Temp.:Inert atmosphere,Room Temperature
Solubility.:soluble in Tetrahydrofuran

Purity/Quality:

97% ^*data from raw suppliers

2-p-TerphenylboronicAcid ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2-P-TERPHENYLBORONIC ACID

There total 2 articles about 2-P-TERPHENYLBORONIC ACID which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 121-43-7,63156-11-6
Trimethyl borate

: 3282-24-4
2-bromo-[1,1';4',1]terphenyl

: 7732-18-5
water

: 663954-31-2
([1,1':4',1''-terphenyl]-2-yl)boronic acid

Guidance literature:: 2-bromo-[1,1';4',1"]terphenyl; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 2h; Schlenk technique;

Trimethyl borate; In tetrahydrofuran; at -78 - 20 ℃; for 10h; Schlenk technique;

water; With hydrogenchloride; In tetrahydrofuran; at 20 ℃; for 1h; pH=6 - 7; Schlenk technique;
DOI:10.1021/acs.orglett.8b02247

Reference yield:

: 121-43-7,63156-11-6
Trimethyl borate

: 3282-24-4
2-bromo-[1,1';4',1]terphenyl

: 663954-31-2
([1,1':4',1''-terphenyl]-2-yl)boronic acid

Guidance literature:: 2-bromo-[1,1';4',1"]terphenyl; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h;

Trimethyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 1h;
DOI:10.1055/s-0035-1561940