Rhodium octanoate dimer

Base Information

• Chemical Name: Rhodium octanoate dimer
• CAS No.: 73482-96-9
• Molecular Formula: C32H60O8Rh2
• Molecular Weight: 778.635
• Hs Code.: 28439000
• DSSTox Substance ID: DTXSID90449464
• Mol file: 73482-96-9.mol

Synonyms:Rhodium octanoate dimer;73482-96-9;octanoic acid;rhodium;Rhodium(II) Octanoate Dimer;Rhodium(II) octanoate;Rhodium (II) octanoate dimer;Rhodium(II)OctanoateDimer;Rhodium( cento)octanoatedimer;DTXSID90449464;MKDJIADBNUOBJH-UHFFFAOYSA-N;FT-0700645

Chemical Property of Rhodium octanoate dimer

Chemical Property:

• Appearance/Colour: green powder
• Vapor Pressure: 0.022mmHg at 25°C
• Boiling Point: 239.3 °C at 760 mmHg
• Flash Point: 107.4 °C
• PSA: 105.20000
• LogP: 9.41760
• Storage Temp.: Inert atmosphere,Room Temperature
• Solubility.: Soluble in hot alcohol, dichloromethane, toluene and acetic acid
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 24
• Exact Mass: 782.27111
• Heavy Atom Count: 42
• Complexity: 89.3

Purity/Quality:

99% ^*data from raw suppliers

Rhodium(II) Octanoate Dimer ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCC(=O)O.CCCCCCCC(=O)O.CCCCCCCC(=O)O.CCCCCCCC(=O)O.[Rh].[Rh]
• Uses: Rhodium(II) Octanoate Dimer is a catalyst which is used in intramolecular cyclization of 1-sulfonyl-1,2,3-triazole and sulfinate.

Technology Process of Rhodium octanoate dimer

There total 4 articles about Rhodium octanoate dimer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.57%

rhodium(III) chloride + Octanoic acid (124-07-2) → rhodium (II) octanoate dimer (73482-96-9)

Guidance literature:

With sodium hydroxide; at 70 ℃; for 4h; Temperature; Large scale;

Reference yield: 94.4%

Octanoic acid (124-07-2) + tetrasodium rhodium tetracarbonate → rhodium (II) octanoate dimer (73482-96-9)

Guidance literature:

In water; at 60 ℃; for 3h;

Reference yield: 67.0%

Octanoic acid (124-07-2) + rhodium(III) trichloride hydrate → rhodium (II) octanoate dimer (73482-96-9)

Guidance literature:

With lithium carbonate; In ethanol; at 20 ℃; for 6.5h; Heating;

DOI:10.1021/acs.oprd.0c00164

upstream raw materials:

Octanoic acid

Downstream raw materials:

benzhydryl 6-oxopenicillinate

Refernces

• 1、 Martínez-Castro, Elisa,Mendoza, Abraham,Suárez-Pantiga, Samuel. "Scalable Synthesis of Esp and Rhodium(II) Carboxylates from Acetylacetone and RhCl3· xH2O". supporting information. p. 1207 - 1212. Retrieved 2020/07/15.
• 2、 -. "Method for preparing dual-core rhodium (II) carboxylate". Paragraph 0022; 0023. . Retrieved 2018/07/06.