carbonyl ruthenium(II) 5,10,15,20-tetra(2,6-dichlorophenyl)porphyrin

Base Information

• Chemical Name: carbonyl ruthenium(II) 5,10,15,20-tetra(2,6-dichlorophenyl)porphyrin
• CAS No.: 127390-19-6
• Molecular Formula: C₄₅H₂₀Cl₈N₄ORu
• Molecular Weight: 1017.37
• Mol file: 127390-19-6.mol

Synonyms:carbonyl ruthenium(II) 5,10,15,20-tetra(2,6-dichlorophenyl)porphyrin

Chemical Property of carbonyl ruthenium(II) 5,10,15,20-tetra(2,6-dichlorophenyl)porphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of carbonyl ruthenium(II) 5,10,15,20-tetra(2,6-dichlorophenyl)porphyrin

There total 3 articles about carbonyl ruthenium(II) 5,10,15,20-tetra(2,6-dichlorophenyl)porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin (37083-37-7) + dodecacarbonyl-triangulo-triruthenium (15243-33-1) → carbonyl ruthenium(II) 5,10,15,20-tetra(2,6-dichlorophenyl)porphyrin (127390-19-6)

Guidance literature:

In 1,2,4-Trichlorobenzene; at 195 - 200 ℃; Inert atmosphere;

DOI:10.1016/j.tetlet.2011.05.081

Reference yield: 99.0%

5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin (37083-37-7) + dodecacarbonyl-triangulo-triruthenium (15243-33-1) → [Ru(2,6-Cl2tpp)CO] (127390-19-6)

Guidance literature:

In 1,2,4-trichorobenzene; Reflux; Inert atmosphere;

DOI:10.1002/adsc.201000455

Reference yield: 81.0%

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + 5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin → carbonyl ruthenium(II) 5,10,15,20-tetra(2,6-dichlorophenyl)porphyrin (127390-19-6)

Guidance literature:

In decalin; Ru-compd. addn. in 12 aliquots to refluxing org. compd. soln. over 3 h,mixt. chromy. (alumina column; solvent elution with hexane and toluene,unreacted org. compd. elution with toluene/CH2Cl2 1:1); Ru-compd. elution with ethyl acetate/CH2Cl2 1:9, crystn. from CH2Cl2/n-heptane 1:1; elem. anal.;

DOI:10.1016/0020-1693(95)04523-6

upstream raw materials:

dodecacarbonyl-triangulo-triruthenium

5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin

Downstream raw materials:

(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato)(dioxo)ruthenium(VI)

trans-dihydroxo-[tetrakis(2,6-dichlorophenyl)porphinato]ruthenium(IV)

Refernces

• 1、 Liang, Qing-Feng,Liu, Juan-Juan,Chen, Jian. "Sandwich structure of a ruthenium porphyrin and an amino acid hydrazide for probing molecular chirality by circular dichroism". supporting information; experimental part. p. 3987 - 3991. Retrieved 2011/08/09.
• 2、 Dubourdeaux, Patrick,Tavares, Manuella,Grand, Andre,Ramasseul, Rene,Marchon, Jean-Claude. "Preparation and crystal structure of trans-dihydroxo-[tetrakis(2,6-dichlorophenyl)porphinato]ruthenium(IV).2toluene". . p. 657 - 660. Retrieved 2008/10/08.