iminobis(4-methoxyphenyl)-λ⁶-sulfanone

Base Information

• Chemical Name: iminobis(4-methoxyphenyl)-λ⁶-sulfanone
• CAS No.: 55440-60-3
• Molecular Formula: C₁₄H₁₅NO₃S
• Molecular Weight: 277.344
• Mol file: 55440-60-3.mol

Synonyms:iminobis(4-methoxyphenyl)-λ⁶-sulfanone

Chemical Property of iminobis(4-methoxyphenyl)-λ⁶-sulfanone

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of iminobis(4-methoxyphenyl)-λ⁶-sulfanone

There total 4 articles about iminobis(4-methoxyphenyl)-λ⁶-sulfanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

N-di-p-methoxybenzenesulfoniodimethylsulfoximinium perchlorate → iminobis(4-methoxyphenyl)-λ6-sulfanone (55440-60-3)

Guidance literature:

With sodium hydroxide; In acetonitrile; at 30 ℃; Rate constant;

Reference yield: 85.0%

bis(4-methoxyphenyl) sulfoxide (1774-36-3) → iminobis(4-methoxyphenyl)-λ6-sulfanone (55440-60-3)

Guidance literature:

With [bis(acetoxy)iodo]benzene; ammonium carbamate; In methanol; at 20 ℃;

DOI:10.1002/anie.201810887

Reference yield:

4-methoxyphenyl magnesium bromide (13139-86-1) → iminobis(4-methoxyphenyl)-λ6-sulfanone (55440-60-3)

Guidance literature:

Multi-step reaction with 2 steps

1: thionyl chloride / tetrahydrofuran / 0 - 20 °C

2: [bis(acetoxy)iodo]benzene; ammonium carbamate / methanol / 20 °C

With thionyl chloride; [bis(acetoxy)iodo]benzene; ammonium carbamate; In tetrahydrofuran; methanol;

DOI:10.1002/anie.201810887

upstream raw materials:

bis(4-methoxyphenyl) sulfoxide

4-methoxyphenyl magnesium bromide