1-Hydroperoxy-2-methyl-cyclohex-2-enecarboxylic acid methyl ester

Base Information

• Chemical Name: 1-Hydroperoxy-2-methyl-cyclohex-2-enecarboxylic acid methyl ester
• CAS No.: 102710-79-2
• Molecular Formula: C₉H₁₄O₄
• Molecular Weight: 186.208
• Mol file: 102710-79-2.mol

Synonyms:1-Hydroperoxy-2-methyl-cyclohex-2-enecarboxylic acid methyl ester

Chemical Property of 1-Hydroperoxy-2-methyl-cyclohex-2-enecarboxylic acid methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 1-Hydroperoxy-2-methyl-cyclohex-2-enecarboxylic acid methyl ester

There total 3 articles about 1-Hydroperoxy-2-methyl-cyclohex-2-enecarboxylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-methyl-1-cyclohexenecarboxylic acid methyl ester (25662-38-8) → 1-Hydroperoxy-2-methylene-cyclohexanecarboxylic acid methyl ester (102710-78-1) + 1-Hydroperoxy-2-methyl-cyclohex-2-enecarboxylic acid methyl ester (102710-79-2) + 6-Hydroperoxy-6-methyl-cyclohex-1-enecarboxylic acid methyl ester (102710-73-6)

Guidance literature:

With oxygen; mesoporphyrin IX dimethylester; In 1,1,2-Trichloro-1,2,2-trifluoroethane; at -15 ℃; Irradiation;

DOI:10.1016/S0040-4039(00)98279-0

Reference yield:

1-Carbomethoxy-2-methylcyclohexa-1,4-dien (50983-22-7) → 1-Hydroperoxy-2-methyl-cyclohex-2-enecarboxylic acid methyl ester (102710-79-2)

Guidance literature:

Multi-step reaction with 2 steps

1: H₂ / Pd/C / benzene

2: 6 percent Chromat_. / ¹O₂ / mesoporphyrin IX dimethylester / 1,1,2-trichloro-1,2,2-trifluoro-ethane / -15 °C / Irradiation

With hydrogen; oxygen; palladium on activated charcoal; mesoporphyrin IX dimethylester; In 1,1,2-Trichloro-1,2,2-trifluoroethane; benzene;

DOI:10.1016/S0040-4039(00)98279-0

Reference yield:

Methyl 2-butynoate (23326-27-4) → 1-Hydroperoxy-2-methyl-cyclohex-2-enecarboxylic acid methyl ester (102710-79-2)

Guidance literature:

Multi-step reaction with 3 steps

2: H₂ / Pd/C / benzene

3: 6 percent Chromat_. / ¹O₂ / mesoporphyrin IX dimethylester / 1,1,2-trichloro-1,2,2-trifluoro-ethane / -15 °C / Irradiation

With hydrogen; oxygen; palladium on activated charcoal; mesoporphyrin IX dimethylester; In 1,1,2-Trichloro-1,2,2-trifluoroethane; benzene;

DOI:10.1016/S0040-4039(00)98279-0

upstream raw materials:

2-methyl-1-cyclohexenecarboxylic acid methyl ester

1-Carbomethoxy-2-methylcyclohexa-1,4-dien

Methyl 2-butynoate