3E-4,8-dimethyl-2-(triisopropylsiloxy)-3-(triisopropylsiloxymethyl)nona-1,3,7-triene

Base Information

Chemical Name:3E-4,8-dimethyl-2-(triisopropylsiloxy)-3-(triisopropylsiloxymethyl)nona-1,3,7-triene
CAS No.:802622-05-5
Molecular Formula:C₃₀H₆₀O₂Si₂
Molecular Weight:508.976
Hs Code.:

Synonyms:3E-4,8-dimethyl-2-(triisopropylsiloxy)-3-(triisopropylsiloxymethyl)nona-1,3,7-triene

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Chemical Property of 3E-4,8-dimethyl-2-(triisopropylsiloxy)-3-(triisopropylsiloxymethyl)nona-1,3,7-triene

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Technology Process of 3E-4,8-dimethyl-2-(triisopropylsiloxy)-3-(triisopropylsiloxymethyl)nona-1,3,7-triene

There total 1 articles about 3E-4,8-dimethyl-2-(triisopropylsiloxy)-3-(triisopropylsiloxymethyl)nona-1,3,7-triene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 802622-03-3
3E-4,8-dimethyl-3-(triisopropylsiloxymethyl)-3,7-nonadien-2-one

: 802622-05-5
3E-4,8-dimethyl-2-(triisopropylsiloxy)-3-(triisopropylsiloxymethyl)nona-1,3,7-triene

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In dichloromethane; at -78 - 0 ℃; for 5h;

Reference yield:

: 2043-21-2
acryloyl-1,3-oxazolidin-2-one

: 802622-05-5
3E-4,8-dimethyl-2-(triisopropylsiloxy)-3-(triisopropylsiloxymethyl)nona-1,3,7-triene

: 3-[(1S,2R)-2-methyl-2-(4-methylpent-3-enyl)-4-(triisopropylsiloxy)-3-(triisopropylsiloxymethyl)cyclohex-3-enecarbonyl]oxazolidin-2-one

: 802622-23-7
3-[(1R,2S)-2-methyl-2-(4-methylpent-3-enyl)-4-(triisopropylsiloxy)-3-(triisopropylsiloxymethyl)cyclohex-3-enecarbonyl]oxazolidin-2-one

Guidance literature:: acryloyl-1,3-oxazolidin-2-one; With silver hexafluoroantimonate; ferric(III) bromide; (R,R)-2,6-bis(4-(4-EtO-C₆H₄)-4,5-H₂-1,3-oxazol-2-yl)pyridine; 5A molecular sieve; In dichloromethane; at 20 ℃; for 0.25h;

3E-4,8-dimethyl-2-(triisopropylsiloxy)-3-(triisopropylsiloxymethyl)nona-1,3,7-triene; In dichloromethane; at -70 ℃; for 30h;

Reference yield:

: 802622-05-5
3E-4,8-dimethyl-2-(triisopropylsiloxy)-3-(triisopropylsiloxymethyl)nona-1,3,7-triene

: 802622-28-2
4-methoxymethoxymethyl-3-methyl-3-(4-methylpent-3-enyl)-2-(triisopropylsiloxymethyl)cyclohexanone

Guidance literature:: Multi-step reaction with 5 steps

1.1: (R,R)-2,6-bis(4-(4-EtO-C₆H₄)-4,5-H₂-1,3-oxazol-2-yl)pyridine; FeBr₃; AgSbF₆ / molecular sieves 5 Angstroem / CH₂Cl₂ / 0.25 h / 20 °C

1.2: CH₂Cl₂ / 30 h / -70 °C

2.1: n-BuLi / tetrahydrofuran; hexane / 0.5 h / 0 °C

2.2: tetrahydrofuran / 0.5 h / 0 °C

3.1: LiAlH₄ / tetrahydrofuran / 0.17 h / 0 °C

4.1: Huenig base; TBAI / 1,2-dichloro-ethane / 2 h / 20 °C

5.1: AcOH; TBAF / tetrahydrofuran / 24 h / 20 °C

5.2: imidazole / dimethylformamide / 22 h / 0 - 20 °C

With silver hexafluoroantimonate; ferric(III) bromide; lithium aluminium tetrahydride; n-butyllithium; tetrabutyl ammonium fluoride; tetra-(n-butyl)ammonium iodide; acetic acid; N-ethyl-N,N-diisopropylamine; (R,R)-2,6-bis(4-(4-EtO-C₆H₄)-4,5-H₂-1,3-oxazol-2-yl)pyridine; 5A molecular sieve; In tetrahydrofuran; hexane; dichloromethane; 1,2-dichloro-ethane; 1.2: enantioselective Diels-Alder reaction;