(Et₄N)[W(OPh)(S₂C₂Me₂)4]

Base Information

Chemical Name:(Et₄N)[W(OPh)(S₂C₂Me₂)4]
CAS No.:262597-63-7
Molecular Formula:C₈H₂₀N*C₁₄H₁₇OS₄W
Molecular Weight:643.656
Hs Code.:

(Et<sub>4</sub>N)[W(OPh)(S<sub>2</sub>C<sub>2</sub>Me<sub>2</sub>)4]

Synonyms:(Et₄N)[W(OPh)(S₂C₂Me₂)4]

Suppliers and Price of (Et₄N)[W(OPh)(S₂C₂Me₂)4]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (Et₄N)[W(OPh)(S₂C₂Me₂)4]

Chemical Property:

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Technology Process of (Et₄N)[W(OPh)(S₂C₂Me₂)4]

There total 2 articles about (Et₄N)[W(OPh)(S₂C₂Me₂)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 12116-98-2
[W^IV(1,2-dimethylethene-1,2-dithiolate)2(CO)2]

: 56-34-8
tetraethylammonium chloride

: 139-02-6
sodium phenoxide

: 262597-63-7
(Et₄N)[W(IV)(OPh)(1,2-dimethyldithiolene)2]

Guidance literature:: In acetonitrile; under anaerobic conditions; reaction of the W complex with 1 equiv. each of NaOPh and Et4NCl at ambient temp.; elem. anal.;
DOI:10.1021/ja001197y

Reference yield: 66.0%

: 12116-98-2
[W(but-2-ene-2,3-dithiolato)₂(CO)₂]

: 56-34-8
tetraethylammonium chloride

: 139-02-6
sodium phenoxide

: 262597-63-7
(Et₄N)[W(OPh)(S₂C₂Me₂)4]

Guidance literature:: In tetrahydrofuran; (N2); NaOPh added to W complex soln., stirred for 90 min, treated with Et4NCl, stirred for 10 min; solvent-removed, solid dissolved in MeCN, filtered, layered with ether,crystd. over 1 d, collected, washed (ether), dried; elem. anal.;
DOI:10.1021/ic991153u

Reference yield: 76.0%

: 262597-63-7
(Et₄N)[W(IV)(OPh)(1,2-dimethyldithiolene)2]

: (Et₄N)[WO(OPh)(S₂C₂Me₂)2]

Guidance literature:: With (CH₃)3NO; In acetonitrile; to a frozen soln. of complex in CH3CN was injected a soln. of Me3NO in CH3CN, warmed to -15°C over 30 min (N2); treated with cold ether (-15°C) and maintained at -20°C over 1 d, the solid was washed with cold ether (-15°C) and dried; elem. anal.;
DOI:10.1021/ja0036559