(R)-dimethyl(phenyl)(3-phenyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)silane

Base Information

Chemical Name:(R)-dimethyl(phenyl)(3-phenyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)silane
CAS No.:1270304-75-0
Molecular Formula:C₂₃H₃₃BO₂Si
Molecular Weight:380.41
Hs Code.:

Synonyms:(R)-dimethyl(phenyl)(3-phenyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)silane

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Chemical Property of (R)-dimethyl(phenyl)(3-phenyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)silane

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Technology Process of (R)-dimethyl(phenyl)(3-phenyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)silane

There total 7 articles about (R)-dimethyl(phenyl)(3-phenyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 185990-03-8
dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane

: 218601-55-9
3-phenylpropyl N,N-diisopropylcarbamate

: 1270304-75-0
(R)-dimethyl(phenyl)(3-phenyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)silane

Guidance literature:: 3-phenylpropyl N,N-diisopropylcarbamate; With sec.-butyllithium; (-)-sparteine; In diethyl ether; hexane; cyclohexane; at -78 ℃; for 5h; Inert atmosphere;

dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane; In diethyl ether; hexane; cyclohexane; at -78 - 23 ℃; Inert atmosphere;
DOI:10.1021/ol200177f

Reference yield:

: 4,4,5,5-tetramethyl-2-(3-phenylpropenyl)[1,3,2]dioxaborolane

: 766-77-8
Dimethylphenylsilane

: 1270304-75-0
(R)-dimethyl(phenyl)(3-phenyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)silane

: (-)-(S)-2-[1-(dimethylphenylsilyl)-3-phenylpropyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With [Pt(1,5-diphenylpenta-1,4-dien-3-one)3]; C₅₁H₆₈NO₁₂P; In tert-butyl methyl ether; at 20 ℃; for 14h; Overall yield = 90 percent; enantioselective reaction;
DOI:10.1021/acscatal.8b00221

Reference yield:

: C₁₅H₂₃BO₃

: 185990-03-8
dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane

: 1270304-75-0
(R)-dimethyl(phenyl)(3-phenyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)silane

Guidance literature:: With sodium t-butanolate; In toluene; at 100 ℃; for 16h; Inert atmosphere; Glovebox; Sealed tube; Schlenk technique;
DOI:10.1021/jacs.7b02518