1,3-cyclooctadiene

Base Information

• Chemical Name: 1,3-cyclooctadiene
• CAS No.: 186983-16-4
• Molecular Formula: C₈H₁₂
• Molecular Weight: 108.183
• Mol file: 186983-16-4.mol

Synonyms:1,3-cyclooctadiene

Chemical Property of 1,3-cyclooctadiene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,3-cyclooctadiene

There total 10 articles about 1,3-cyclooctadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

cyclo-octa-1,5-diene (5259-72-3,10060-40-9,111-78-4) → 1,3-cyclooctadiene (186983-16-4) + 1,4-cyclooctadiene (1073-07-0,502698-71-7,16327-22-3)

Guidance literature:

With oxygen; palladium diacetate; scandium tris(trifluoromethanesulfonate); In water; acetonitrile; at 90 ℃; for 24h; under 15201 Torr; Reagent/catalyst; Kinetics; Autoclave;

DOI:10.1039/c5dt02612a

Reference yield:

1,5-cis,cis-cyclooctadiene (1552-12-1,111-78-4) → 9-oxa-bicyclo[4.2.1]nonane (284-20-8) + 9-oxabicyclo[3.3.1]nonane (281-05-0) + bicyclo[3.3.0]oct-2-ene (5549-09-7) + 1,3-cyclooctadiene (186983-16-4)

Guidance literature:

With tetrachloromethane; copper(II) choride dihydrate; chromium(III) acetylacetonate; water; at 160 ℃; for 6h; Autoclave;

DOI:10.1134/S0965544111060107

Reference yield:

1,5-cis,cis-cyclooctadiene (1552-12-1,111-78-4) → 9-oxa-bicyclo[4.2.1]nonane (284-20-8) + 9-oxabicyclo[3.3.1]nonane (281-05-0) + bicyclo[3.3.0]oct-2-ene (5549-09-7) + 5-chlorocyclooct-1-ene (1855-55-6) + 1,3-cyclooctadiene (186983-16-4)

Guidance literature:

With tetrachloromethane; copper(II) choride dihydrate; chromium(III) acetylacetonate; water; at 150 ℃; for 6h; Autoclave;

DOI:10.1134/S0965544111060107

upstream raw materials:

cyclo-octa-1,5-diene

1,5-cis,cis-cyclooctadiene

Cyclooctan

tert-butylethylene

Downstream raw materials:

1,3-cyclooctadiene oxide

(3aS,6aS)-1,2,3,3a,4,6a-Hexahydro-pentalene

9-oxa-bicyclo[4.2.1]-7-nonene

9,10-dioxabicyclo[4.2.2]dec-7-ene