N-<(E)-1-Methyl-3-phenylallyl>-N-(p-toluolsulfonamidothio)-p-toluolsulfonamid

Base Information

• Chemical Name: N-<(E)-1-Methyl-3-phenylallyl>-N-(p-toluolsulfonamidothio)-p-toluolsulfonamid
• CAS No.: 74608-01-8
• Molecular Formula: C₂₄H₂₆N₂O₄S₃
• Molecular Weight: 502.679
• Mol file: 74608-01-8.mol

Synonyms:N-<(E)-1-Methyl-3-phenylallyl>-N-(p-toluolsulfonamidothio)-p-toluolsulfonamid

Chemical Property of N-<(E)-1-Methyl-3-phenylallyl>-N-(p-toluolsulfonamidothio)-p-toluolsulfonamid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-<(E)-1-Methyl-3-phenylallyl>-N-(p-toluolsulfonamidothio)-p-toluolsulfonamid

There total 2 articles about N-<(E)-1-Methyl-3-phenylallyl>-N-(p-toluolsulfonamidothio)-p-toluolsulfonamid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

trans-1-phenyl-1-butene (1005-64-7) + bis(p-toluenesulfonyl) sulfur diimide (851-06-9) → N-<(E)-1-Methyl-3-phenylallyl>-N-(p-toluolsulfonamidothio)-p-toluolsulfonamid (74608-01-8)

Guidance literature:

In toluene; at 20 ℃; for 9h;

Reference yield:

toluene-4-sulfonamide (70-55-3) → N-<(E)-1-Methyl-3-phenylallyl>-N-(p-toluolsulfonamidothio)-p-toluolsulfonamid (74608-01-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 75 percent / SOCl₂ / various solvent(s) / 1) 8 h, 80 deg C

2: 93 percent / toluene / 9 h / 20 °C

With thionyl chloride; In toluene;

Reference yield: 79.0%

N-<(E)-1-Methyl-3-phenylallyl>-N-(p-toluolsulfonamidothio)-p-toluolsulfonamid (74608-01-8) → 4-methyl-N-[(2E)-1-methyl-3-phenyl-2-propen-1-yl]benzenesulfonamide (74608-23-4)

Guidance literature:

With water; In triethylamine; at 20 ℃; for 3h;

upstream raw materials:

trans-1-phenyl-1-butene

bis(p-toluenesulfonyl) sulfur diimide

toluene-4-sulfonamide

Downstream raw materials:

4-methyl-N-[(2E)-1-methyl-3-phenyl-2-propen-1-yl]benzenesulfonamide