2-<(tert-butyl)dimethylsilyl>-4-<(tert-butyl)dimethylsilyloxy>-7-(2',2'-dimethyl-6'-mthylidenecyclohexyl)-3-oxa-1-heptene

Base Information

Chemical Name:2-<(tert-butyl)dimethylsilyl>-4-<(tert-butyl)dimethylsilyloxy>-7-(2',2'-dimethyl-6'-mthylidenecyclohexyl)-3-oxa-1-heptene
CAS No.:556076-23-4
Molecular Formula:C₂₇H₅₄O₂Si₂
Molecular Weight:466.896
Hs Code.:

Synonyms:2-<(tert-butyl)dimethylsilyl>-4-<(tert-butyl)dimethylsilyloxy>-7-(2',2'-dimethyl-6'-mthylidenecyclohexyl)-3-oxa-1-heptene

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Chemical Property of 2-<(tert-butyl)dimethylsilyl>-4-<(tert-butyl)dimethylsilyloxy>-7-(2',2'-dimethyl-6'-mthylidenecyclohexyl)-3-oxa-1-heptene

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Technology Process of 2-<(tert-butyl)dimethylsilyl>-4-<(tert-butyl)dimethylsilyloxy>-7-(2',2'-dimethyl-6'-mthylidenecyclohexyl)-3-oxa-1-heptene

There total 8 articles about 2-<(tert-butyl)dimethylsilyl>-4-<(tert-butyl)dimethylsilyloxy>-7-(2',2'-dimethyl-6'-mthylidenecyclohexyl)-3-oxa-1-heptene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

: 95452-00-9
4-(2',2'-dimethyl-6'-methylenecyclohexyl)-1-<(tert-butyl)dimethylsilyl>-1-butanone

: 2-ethenyl-1,1-dimethyl-3-methylene-cyclohexane

: 95452-13-4
4-(2',2'-dimethyl-6'-methylidenecyclohexyl)butanal

: 3-<(tert-butyl)dimethylsilyloxy>-8,8-dimethyltricyclo<5.4.0.0^1,3>undecane

: 95452-12-3
4-(2',2'-dimethyl-6'-methylidenecyclohexyl)butanal-bis<(tert-butyl)dimethylsilyl>-acetal

: 556076-23-4
2-<(tert-butyl)dimethylsilyl>-4-<(tert-butyl)dimethylsilyloxy>-7-(2',2'-dimethyl-6'-mthylidenecyclohexyl)-3-oxa-1-heptene

: (Z)-1-<(tert-butyl)dimethylsilyloxy>-4-(2',2'-dimethylidenecyclohexyl)-1-butene

Guidance literature:: In acetonitrile; Product distribution; Irradiation; investigation of the photolyses of the acylsilane;
DOI:10.1002/hlca.19840670711

Reference yield: 11.0%

: 95452-00-9
4-(2',2'-dimethyl-6'-methylenecyclohexyl)-1-<(tert-butyl)dimethylsilyl>-1-butanone

: 2-ethenyl-1,1-dimethyl-3-methylene-cyclohexane

: 3-<(tert-butyl)dimethylsilyloxy>-8,8-dimethyltricyclo<5.4.0.0^1,3>undecane

: 556076-23-4
2-<(tert-butyl)dimethylsilyl>-4-<(tert-butyl)dimethylsilyloxy>-7-(2',2'-dimethyl-6'-mthylidenecyclohexyl)-3-oxa-1-heptene

Guidance literature:: In tetrahydrofuran; Irradiation;
DOI:10.1002/hlca.19840670711

Reference yield:

: 13720-12-2
4-(2',2'-Dimethyl-6'-methylidenecyclohexyl)butan-2-one

: 556076-23-4
2-<(tert-butyl)dimethylsilyl>-4-<(tert-butyl)dimethylsilyloxy>-7-(2',2'-dimethyl-6'-mthylidenecyclohexyl)-3-oxa-1-heptene

Guidance literature:: Multi-step reaction with 7 steps

1: 1) I₂, 2) 2N NaOH / 1) pyridine, 100 deg C, 1 h; 2) 100 deg C, overnight

2: 88 percent / LiAlH₄ / diethyl ether / 2 h / Ambient temperature

3: 81 percent / pyridine / 0.08 h / Ambient temperature

4: 96 percent / NaI / 1,2-dimethoxy-ethane / 18 h / 50 °C

5: 92 percent / BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide; hexane / 2.5 h / Ambient temperature

6: 54 percent / Tl(NO₃)3*3H₂O / tetrahydrofuran; H₂O; methanol / 0.08 h / Ambient temperature

7: 11 percent / tetrahydrofuran / Irradiation

With pyridine; sodium hydroxide; lithium aluminium tetrahydride; n-butyllithium; iodine; thallium(III) nitrate; sodium iodide; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; 1,2-dimethoxyethane; diethyl ether; hexane; water;
DOI:10.1002/hlca.19840670711