tert-butyldiphenylsilyl 2-<6-(2,4-dinitrophenoxy)hexyl>oxiranecarboxylate

Base Information

Chemical Name:tert-butyldiphenylsilyl 2-<6-(2,4-dinitrophenoxy)hexyl>oxiranecarboxylate
CAS No.:220077-64-5
Molecular Formula:C₃₁H₃₆N₂O₈Si
Molecular Weight:592.721
Hs Code.:

Synonyms:tert-butyldiphenylsilyl 2-<6-(2,4-dinitrophenoxy)hexyl>oxiranecarboxylate

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Chemical Property of tert-butyldiphenylsilyl 2-<6-(2,4-dinitrophenoxy)hexyl>oxiranecarboxylate

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Technology Process of tert-butyldiphenylsilyl 2-<6-(2,4-dinitrophenoxy)hexyl>oxiranecarboxylate

There total 4 articles about tert-butyldiphenylsilyl 2-<6-(2,4-dinitrophenoxy)hexyl>oxiranecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 220077-63-4
tert-butyldiphenylsilyl 2-methylene-8-(2,4-dinitrophenoxy)octanoate

: 220077-64-5
tert-butyldiphenylsilyl 2-<6-(2,4-dinitrophenoxy)hexyl>oxiranecarboxylate

Guidance literature:: With 3-methyl-4-hydroxy-5-tert-butylbenzenethiol; 3-chloro-benzenecarboperoxoic acid; In 1,2-dichloro-ethane; at 60 ℃; for 14h;
DOI:10.1016/S0968-0896(98)00175-8

Reference yield:

: 220077-61-2
2-methylene-8-phenoxyoctanoic acid

: 220077-64-5
tert-butyldiphenylsilyl 2-<6-(2,4-dinitrophenoxy)hexyl>oxiranecarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 93.8 percent / NO₂BF₄ / CH₂Cl₂ / 0.5 h

2: 74.3 percent / DBU / benzene / 1 h / 25 °C

3: 96 percent / MCPBA, 3-tert-butyl-4-hydroxy-5-methylphenylsulfide / 1,2-dichloro-ethane / 14 h / 60 °C

With nitronium tetrafluoborate; 3-methyl-4-hydroxy-5-tert-butylbenzenethiol; 1,8-diazabicyclo[5.4.0]undec-7-ene; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; 1,2-dichloro-ethane; benzene;
DOI:10.1016/S0968-0896(98)00175-8

Reference yield:

: 220077-60-1
ethyl 2-methylene-8-phenoxyoctanoate

: 220077-64-5
tert-butyldiphenylsilyl 2-<6-(2,4-dinitrophenoxy)hexyl>oxiranecarboxylate

Guidance literature:: Multi-step reaction with 4 steps

1: 88.9 percent / KOH / ethanol / 8 h / 25 °C

2: 93.8 percent / NO₂BF₄ / CH₂Cl₂ / 0.5 h

3: 74.3 percent / DBU / benzene / 1 h / 25 °C

4: 96 percent / MCPBA, 3-tert-butyl-4-hydroxy-5-methylphenylsulfide / 1,2-dichloro-ethane / 14 h / 60 °C

With potassium hydroxide; nitronium tetrafluoborate; 3-methyl-4-hydroxy-5-tert-butylbenzenethiol; 1,8-diazabicyclo[5.4.0]undec-7-ene; 3-chloro-benzenecarboperoxoic acid; In ethanol; dichloromethane; 1,2-dichloro-ethane; benzene;
DOI:10.1016/S0968-0896(98)00175-8