Aluminium-nickel

Base Information

• Chemical Name: Aluminium-nickel
• CAS No.: 12635-29-9
• Molecular Formula: AlNi
• Molecular Weight: 85.67
• Hs Code.: 38151900
• European Community (EC) Number: 234-439-6,682-897-4,684-239-1
• DSSTox Substance ID: DTXSID0065145,DTXSID10276552
• Mol file: 12635-29-9.mol

Synonyms:Aluminium-nickel;12635-29-9;12003-78-0;12635-27-7;aluminum;nickel;nickel aluminum;nickel-aluminum;Aluminum-nickel catalyst;Aluminium nickel, Al/Ni 50/50;Al.Ni;aluminum-nickel;aluminium nickel;nickel aluminium;nickel-aluminium;Nickel aluminide;Niquel Aluminium;Raney nickel aluminium;Nickel Aluminide Powder;Catalyseur d'aluminium-nickel;KSC005Q4L;DTXSID0065145;DTXSID10276552;NPXOKRUENSOPAO-UHFFFAOYSA-N;EINECS 234-439-6;AKOS015833427;AKOS015903659;Aluminium, compound with nickel (1:1);FT-0622245;Nickel aluminum, 99.0% min (metals basis);Raney(R) Nickel Catalyst, 50% slurry in H2O;Aluminum-nickel catalyst, Al-Ni 50:50 wt. %;Raney Nickel (R)2800 slurry, in H2O, active catalyst;Raney(R)-Nickel, W.R. Grace and Co. Raney(R)2400, slurry, in H2O, active catalyst;Raney(R)-Nickel, W.R. Grace and Co. Raney(R)2800, slurry, in H2O, active catalyst;Raney(R)-Nickel, W.R. Grace and Co. Raney(R)3202, slurry, in H2O, active catalyst;Raney(R)-Nickel, W.R. Grace and Co. Raney(R)4200, slurry, in H2O, active catalyst;12704-83-5

Chemical Property of Aluminium-nickel

Chemical Property:

• Appearance/Colour: grey powder
• Melting Point: 1350 °C
• PSA: 0.00000
• Density: 3.46 g/cm³
• LogP: 0.33750
• Storage Temp.: Flammables area
• Water Solubility.: INSOLUBLE
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 84.916880
• Heavy Atom Count: 2
• Complexity: 0

Purity/Quality:

≥97% ^*data from raw suppliers

Nickel Aluminum ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F, Xn
• Hazard Codes: F,Xn
• Statements: 17-40-43-15-42/43
• Safety Statements: 5-15-22-36-7/8-43A-45-36/37

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Nickel Compounds, Inorganic
• Canonical SMILES: [Al].[Ni]
• Uses: Nickel Aluminum is used for preparation of Raney Nickel catalyst.

Refernces

Backbone extended pyrrolidine PNA (bepPNA): A chiral PNA for selective RNA recognition

10.1016/j.tet.2005.12.002

The study focuses on the synthesis and characterization of a novel cationic, chiral peptide nucleic acid (PNA) analogue known as backbone extended pyrrolidine PNA (bepPNA), which is designed for selective recognition of RNA over DNA. The bepPNA features an additional carbon atom in the backbone and a (2S,4S) geometry of the pyrrolidine ring, optimizing the internucleobase distance for triplex mode binding. The researchers used various chemicals in the synthesis process, including trans-4-hydroxy-L-proline, LiCl/NaBH4 for reduction, p-TsCl for tosylation, NaN3 for azide formation, Raney Ni for reduction, BocN3 for protection, and Pd–C catalyst for hydrogenation. These chemicals served to protect, modify, and transform the PNA structure at different stages of the synthesis. The study also involved the use of UV–Tm measurements, gel electrophoretic shift assays, and circular dichroism analysis to evaluate the binding properties of bepPNA in both triplex and duplex modes. The purpose of these chemicals and methods was to create a PNA analogue with improved binding affinity and selectivity towards RNA, which has potential applications in gene-targeted therapeutics and molecular diagnostics.

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