allyl 3-(3-chlorophenyl)propiolate

Base Information

• Chemical Name: allyl 3-(3-chlorophenyl)propiolate
• CAS No.: 1372715-24-6
• Molecular Formula: C₁₂H₉ClO₂
• Molecular Weight: 220.655
• Mol file: 1372715-24-6.mol

Synonyms:allyl 3-(3-chlorophenyl)propiolate

Chemical Property of allyl 3-(3-chlorophenyl)propiolate

Chemical Property:

Purity/Quality:

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Technology Process of allyl 3-(3-chlorophenyl)propiolate

There total 1 articles about allyl 3-(3-chlorophenyl)propiolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-(3-chlorophenyl)prop-2-ynoic acid (7396-28-3) + allyl alcohol (107-18-6) → allyl 3-(3-chlorophenyl)propiolate (1372715-24-6)

Guidance literature:

3-(3-chlorophenyl)prop-2-ynoic acid; allyl alcohol; With dmap; In dichloromethane; at 0 ℃; for 0.25h;

With dicyclohexyl-carbodiimide; In dichloromethane;

DOI:10.1002/anie.201106619

Reference yield: 48.0%

allyl 3-(3-chlorophenyl)propiolate (1372715-24-6) + Methyl phenyldiazoacetate (22979-35-7) → methyl 2-(2-(3-chlorophenyl)ethynyl)-2-phenylpent-4-enoate (1372715-36-0)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In toluene; at 90 ℃; for 11.5h; Inert atmosphere;

DOI:10.1002/anie.201106619

upstream raw materials:

3-(3-chlorophenyl)prop-2-ynoic acid

allyl alcohol

Downstream raw materials:

methyl 2-(2-(3-chlorophenyl)ethynyl)-2-phenylpent-4-enoate