triisopropoxytitanium phenylacetyilide

Base Information

Chemical Name:triisopropoxytitanium phenylacetyilide
CAS No.:101946-72-9
Molecular Formula:C₁₇H₂₆O₃Ti
Molecular Weight:326.272
Hs Code.:

Synonyms:triisopropoxytitanium phenylacetyilide

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Chemical Property of triisopropoxytitanium phenylacetyilide

Chemical Property:

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Technology Process of triisopropoxytitanium phenylacetyilide

There total 2 articles about triisopropoxytitanium phenylacetyilide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 20717-86-6
triisopropoxytitanium(IV) chloride

: 536-74-3
phenylacetylene

: 101946-72-9
triisopropoxytitanium phenylacetyilide

Guidance literature:: With n-butyllithium; In hexane; under Ar, n-BuLi in hexane is added dropwise to soln. of phenylacetylene in THF at 0°C, cooling to -50°C, ClTi(Oi-Pr)3 in hexane is added dropwise, 15 min at -50°C; not isolated;

Reference yield:

: 20717-86-6
triisopropoxytitanium(IV) chloride

: 4440-01-1
lithium phenylacetylide

: 101946-72-9
triisopropoxytitanium phenylacetyilide

Guidance literature:: In diethyl ether; addn. of a soln. of Ti compound to soln. of organic compound at -78°C;;
DOI:10.1016/0022-328X(85)80160-1

Reference yield:

: 101946-72-9
triisopropoxytitanium phenylacetyilide

: 6-methyl-4,8-dioxo-1,3,6,2-dioxazaborocane-2-carbaldehyde

: 6-methyl-2-(3-phenylpropioloyl)-1,3,6,2-dioxazaborocane-4,8-dione

Guidance literature:: Multi-step reaction with 2 steps

1: 1.5 h / -40 - 0 °C

2: Dess-Martin periodane / chloroform; acetonitrile / 0.5 h / 20 °C

With Dess-Martin periodane; In chloroform; acetonitrile;
DOI:10.1002/anie.202007651