Methanesulfonic acid (6R,8S)-8-methanesulfonyloxymethyl-5-trityloxymethyl-1,6,7,8-tetrahydro-cyclopenta[g]indol-6-ylmethyl ester

Base Information

Chemical Name:Methanesulfonic acid (6R,8S)-8-methanesulfonyloxymethyl-5-trityloxymethyl-1,6,7,8-tetrahydro-cyclopenta[g]indol-6-ylmethyl ester
CAS No.:176979-92-3
Molecular Formula:C₃₅H₃₅NO₇S₂
Molecular Weight:645.797
Hs Code.:

Synonyms:Methanesulfonic acid (6R,8S)-8-methanesulfonyloxymethyl-5-trityloxymethyl-1,6,7,8-tetrahydro-cyclopenta[g]indol-6-ylmethyl ester

Suppliers and Price of Methanesulfonic acid (6R,8S)-8-methanesulfonyloxymethyl-5-trityloxymethyl-1,6,7,8-tetrahydro-cyclopenta[g]indol-6-ylmethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Methanesulfonic acid (6R,8S)-8-methanesulfonyloxymethyl-5-trityloxymethyl-1,6,7,8-tetrahydro-cyclopenta[g]indol-6-ylmethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Methanesulfonic acid (6R,8S)-8-methanesulfonyloxymethyl-5-trityloxymethyl-1,6,7,8-tetrahydro-cyclopenta[g]indol-6-ylmethyl ester

There total 3 articles about Methanesulfonic acid (6R,8S)-8-methanesulfonyloxymethyl-5-trityloxymethyl-1,6,7,8-tetrahydro-cyclopenta[g]indol-6-ylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 124-63-0
methanesulfonyl chloride

: 176979-91-2
((6R,8S)-8-Hydroxymethyl-5-trityloxymethyl-1,6,7,8-tetrahydro-cyclopenta[g]indol-6-yl)-methanol

: 176979-92-3
Methanesulfonic acid (6R,8S)-8-methanesulfonyloxymethyl-5-trityloxymethyl-1,6,7,8-tetrahydro-cyclopenta[g]indol-6-ylmethyl ester

Guidance literature:: With triethylamine; In diethyl ether; at 0 ℃; for 4h;
DOI:10.1021/jo951767q

Reference yield:

: 176980-00-0
(6R,8S)-1-(2,2-Dimethyl-propionyl)-5-trityloxymethyl-1,6,7,8-tetrahydro-cyclopenta[g]indole-6,8-dicarbaldehyde

: 176979-92-3
Methanesulfonic acid (6R,8S)-8-methanesulfonyloxymethyl-5-trityloxymethyl-1,6,7,8-tetrahydro-cyclopenta[g]indol-6-ylmethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 88 percent / sodium borohydride / methanol / 2 h / Ambient temperature

2: 83 percent / triethylamine / diethyl ether / 4 h / 0 °C

With sodium tetrahydroborate; triethylamine; In methanol; diethyl ether;
DOI:10.1021/jo951767q

Reference yield:

: (6S,9R)-1-(2,2-dimethyl-1-oxopropyl)-6,7,8,9-tetrahydro-5-[(triphenylmethoxy)methyl]-7,8-dihydroxy-6,9-methano-1H-benz[g]indole

: 176979-92-3
Methanesulfonic acid (6R,8S)-8-methanesulfonyloxymethyl-5-trityloxymethyl-1,6,7,8-tetrahydro-cyclopenta[g]indol-6-ylmethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 96 percent / sodium periodate / tetrahydrofuran; H₂O / 1 h / Ambient temperature

2: 88 percent / sodium borohydride / methanol / 2 h / Ambient temperature

3: 83 percent / triethylamine / diethyl ether / 4 h / 0 °C

With sodium tetrahydroborate; sodium periodate; triethylamine; In tetrahydrofuran; methanol; diethyl ether; water;
DOI:10.1021/jo951767q