trans-bis-[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)

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Chemical Name:trans-bis-[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)
CAS No.:1312897-23-6
Molecular Formula:C₁₅₈H₂₂₀N₈P₂PtSi₂Zn₂
Molecular Weight:2675.52
Hs Code.:

trans-bis-[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)

Synonyms:trans-bis-[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)

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Chemical Property of trans-bis-[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)

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Technology Process of trans-bis-[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)

There total 1 articles about trans-bis-[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 15391-01-2,15076-72-9,15390-92-8
trans-dichloro-bis(tri-n-butylphosphine)platinum(II)

: 1312897-29-2
Zn(C₆H₁₃)4(CH₃)4C₂₀H₂N₄(C₆H₄C₂(Si(CH₃)3))(C₆H₄C₂H)

: 1312897-23-6
trans-bis-[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)

Guidance literature:: With CuCl; In dichloromethane; diethylamine; porphyrin, platinum complex and CuCl were dissolved in CH2Cl2/Et2NH (1:1, v/v), stirred at room temp. for 20 min; evapd. in vac., crystd. from CH2Cl2-MeOH, washed with MeOH, collected with CH2Cl2, evapd. in vac., crystd. from CH2Cl2-MeOH;
DOI:10.1039/c0nj00819b

Reference yield: 99.0%

: 1312897-23-6
trans-bis-[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)

: 1312897-33-8
trans-bis[5,15-bis(4-ethynylphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)

Guidance literature:: With (C₄H₉)4NF; In tetrahydrofuran; 1.0 M soln. of NBu4F in THF was added to soln. of porphyrin in THF, stirred at room temp. for 20 min; evapd. in vac., crystd. from CH2Cl2-MeOH, washed with MeOH, collected with CH2Cl2, evapd. in vac., crystd. from CH2Cl2-MeOH;
DOI:10.1039/c0nj00819b