trans-bis[5,15-bis(4-ethynylphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)

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Chemical Name:trans-bis[5,15-bis(4-ethynylphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)
CAS No.:1312897-33-8
Molecular Formula:C₁₅₂H₂₀₄N₈P₂PtZn₂
Molecular Weight:2531.15
Hs Code.:

Synonyms:trans-bis[5,15-bis(4-ethynylphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)

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Chemical Property of trans-bis[5,15-bis(4-ethynylphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)

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Technology Process of trans-bis[5,15-bis(4-ethynylphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)

There total 1 articles about trans-bis[5,15-bis(4-ethynylphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 1312897-23-6
trans-bis-[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)

: 1312897-33-8
trans-bis[5,15-bis(4-ethynylphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)

Guidance literature:: With (C₄H₉)4NF; In tetrahydrofuran; 1.0 M soln. of NBu4F in THF was added to soln. of porphyrin in THF, stirred at room temp. for 20 min; evapd. in vac., crystd. from CH2Cl2-MeOH, washed with MeOH, collected with CH2Cl2, evapd. in vac., crystd. from CH2Cl2-MeOH;
DOI:10.1039/c0nj00819b

Reference yield: 98.0%

: 1312897-19-0
trans-chloro[5-(4-ethynylphenyl)-15-[4-(trimethylsilyl)ethynylphenyl]-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)

: 1312897-33-8
trans-bis[5,15-bis(4-ethynylphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetrakis(n-hexyl)-zinc(II)-porphyrin]bis(tri-n-butyl-phosphine)-platinum(II)

: 3Pt⁽²⁺⁾*4Zn⁽²⁺⁾*2(CH₃)3SiCCC₆H₄(C₆H₁₃)4(CH₃)4C₂₀H₂N₄C₆H₄C₂^(3-)*2CCC₆H₄(C₆H₁₃)4(CH₃)4C₂₀H₂N₄C₆H₄C₂^(4-)*6P(C₄H₉)3

Guidance literature:: With CuCl; In dichloromethane; diethylamine; mixt. of porphyrins and CuCl was dissolved in CH2Cl2/Et2NH (1:1, v/v), stirred at room temp. for 30 min; evapd. in vac., crystd. from CH2Cl2-MeOH, washed with MeOH, collected with CH2Cl2, evapd. in vac., crystd. from CH2Cl2-MeOH;
DOI:10.1039/c0nj00819b