1-bromo-2-hexadecyloxy-4-iodobenzene

Base Information

• Chemical Name: 1-bromo-2-hexadecyloxy-4-iodobenzene
• CAS No.: 1313809-05-0
• Molecular Formula: C₂₂H₃₆BrIO
• Molecular Weight: 523.336
• Mol file: 1313809-05-0.mol

Synonyms:1-bromo-2-hexadecyloxy-4-iodobenzene

Chemical Property of 1-bromo-2-hexadecyloxy-4-iodobenzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-bromo-2-hexadecyloxy-4-iodobenzene

There total 1 articles about 1-bromo-2-hexadecyloxy-4-iodobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

2-bromo-5-iodophenol (932372-99-1) + 1-iodohexadecane (544-77-4) → 1-bromo-2-hexadecyloxy-4-iodobenzene (1313809-05-0)

Guidance literature:

With potassium carbonate; potassium iodide; In N,N-dimethyl-formamide; at 60 ℃; for 24h; Inert atmosphere;

DOI:10.1021/ja203536t

Reference yield: 91.0%

[(3-cyanopropyl)diisopropylsilyl]acetylene (1057407-31-4) + 1-bromo-2-hexadecyloxy-4-iodobenzene (1313809-05-0) + trimethylsilylacetylene (1066-54-2) → C39H65NOSi2

Guidance literature:

[(3-cyanopropyl)diisopropylsilyl]acetylene; 1-bromo-2-hexadecyloxy-4-iodobenzene; With piperidine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triphenylphosphine; at 20 ℃; Inert atmosphere; Schlenk technique;

trimethylsilylacetylene; Inert atmosphere; Schlenk technique;

DOI:10.1039/c8cc04403a

Reference yield: 86.0%

[(3-cyanopropyl)diisopropylsilyl]acetylene (1057407-31-4) + 1-bromo-2-hexadecyloxy-4-iodobenzene (1313809-05-0) + trimethylsilylacetylene (1066-54-2) → C39H65NOSi2

Guidance literature:

1-bromo-2-hexadecyloxy-4-iodobenzene; trimethylsilylacetylene; With piperidine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triphenylphosphine; In tetrahydrofuran; at 20 ℃; for 20h;

[(3‐cyanopropyl)diisopropylsilyl]acetylene; In tetrahydrofuran; at 55 ℃; for 24h;

DOI:10.1002/anie.202111869

upstream raw materials:

2-bromo-5-iodophenol

1-iodohexadecane

Downstream raw materials:

C₃₈H₆₆OSi₂

C₃₅H₅₈OSi