tetraethylammonium p-chlorothiophenolate

Base Information

• Chemical Name: tetraethylammonium p-chlorothiophenolate
• CAS No.: 84143-01-1
• Molecular Formula: C₆H₄ClS*C₈H₂₀N
• Molecular Weight: 273.87
• Mol file: 84143-01-1.mol

Synonyms:tetraethylammonium p-chlorothiophenolate

Chemical Property of tetraethylammonium p-chlorothiophenolate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of tetraethylammonium p-chlorothiophenolate

There total 1 articles about tetraethylammonium p-chlorothiophenolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetraethylammonium chloride (56-34-8) + p-Chlorothiophenol (106-54-7) → tetraethylammonium p-chlorothiophenolate (84143-01-1)

Guidance literature:

With sodium methylate; In methanol; for 4h;

DOI:10.1021/ja00341a029

Reference yield: 86.0%

[Co2(μ-Cl)2(NO)4] + tetraethylammonium p-chlorothiophenolate (84143-01-1) → (Et4N)[Co(SPh-p-Cl)2(NO)2]

Guidance literature:

In tetrahydrofuran; for 2h; Solvent; Inert atmosphere;

DOI:10.1021/acs.inorgchem.5b00883

Reference yield: 77.0%

(Et4N)4[W2FeS8(S-p-C6H4Cl)6(3,6-(C3H5)2cat)2] (84143-03-3) + tetraethylammonium p-chlorothiophenolate (84143-01-1) → (Et4N)3[WFe3S4(S-p-C6H4Cl)4((C3H5)2cat)] (84130-54-1)

Guidance literature:

In acetonitrile; (Et4N)4(W2Fe6S8(S-p-C6H4Cl)6((C3H5)2cat)2) was dissolved in acetonitrile, filtered, to the filtrate was added soln. of (Et4N)(S-p-C6H4Cl) in acetonitrile, stirred for 30 min under N2; volume was reduced, pptn. with diethyl ether, the mixture was maintained at -20°C for 20 h, filtration, drying in vac.; elem. anal.;

DOI:10.1021/ja00341a029

upstream raw materials:

tetraethylammonium chloride

p-Chlorothiophenol

Downstream raw materials:

3(C₂H₅)4N⁽¹⁺⁾*{MoFe₃S₄(SC₆H₄Cl)4(C₆H₂O₂(CH₂CHCH₂)2)}^(3-)=((C₂H₅)4N)3{MoFe₃S₄(SC₆H₄Cl)4(C₆H₂O₂(CH₂CHCH₂)2)}

3(C₂H₅)4N⁽¹⁺⁾*MoFe₃S₄(SC₆H₄Cl)3(C₆H₂(C₂H₅)2O₂)SC₆H₄Cl^(3-)

(Et₄N)3[WFe₃S₄(S-p-C₆H₄Cl)4((C₃H₅)2cat)]