FcMe₂SiCH₂Cl

Base Information

Chemical Name:FcMe₂SiCH₂Cl
CAS No.:260415-45-0
Molecular Formula:C₁₃H₁₇ClFeSi
Molecular Weight:292.663
Hs Code.:

Synonyms:FcMe₂SiCH₂Cl

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Chemical Property of FcMe₂SiCH₂Cl

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Technology Process of FcMe₂SiCH₂Cl

There total 1 articles about FcMe₂SiCH₂Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 1271-15-4
lithiumferrocene

: 421-21-6
(chloromethyl)dimethylfluorosilane

: 102-54-5,55404-68-7
ferrocene

: 260415-45-0
FcMe₂SiCH₂Cl

Guidance literature:: In hexane; under N2 atm. lithioferrocene was added at -78°C to stirred soln. (chloromethyl)dimethylfluorosilane in hexane, react. mixt. was stirredovernight at room temp.; react. mixt. was cooled to 0°C and hydrolized with water, mixt. was filtered, organic layer was dried over Na2SO4, solvent was removed in vacuo, by-products were removed by sublimation and product was distilled in vacuo;

Reference yield: 77.0%

: 260415-45-0
FcMe₂SiCH₂Cl

: 260415-55-2
1,1'-bis([(diphenylchlorostannyl)methyl]dimethylsilyl)ferrocene

: 1,1'-bis([(((ferrocenyldimethylsilyl)methyl)diphenylstannyl)methyl]dimethylsilyl)ferrocene

Guidance literature:: With Mg; In tetrahydrofuran; under N2 atm. soln. fc(SiMe2CH2SnClPh2)2 in THF was added dropwise to soln. 2 equiv. FcMe2SiCH2MgCl prepared from FcMe2SiCH2Cl and Mg in THF, react. mixt. was heated at reflux for 2 h; THF waspartially distilled off, CH2Cl2 was added, and react. mixt. was hydrolyzed with water, mixt. was filtered, org. layer was separated and dried over Na2SO4, solvent was evapd., product was purified by size-exclusion chromy.; elem. anal.;

Reference yield: 64.0%

: 260415-45-0
FcMe₂SiCH₂Cl

: 164527-15-5
bis(diphenylfluorostannyl)methane

: bis([(ferrocenyldimethylsilyl)methyl]diphenylstannyl)methane

Guidance literature:: With Mg; In tetrahydrofuran; under N2 atm. soln. (Ph2FSn)2CH2 in THF was added dropwise to stirred soln. FcMe2SiCH2MgCl prepared from FcMe2SiCH2Cl and Mg in THF, react. mixt. was heated at reflux overnight; THF was partially distilled off, CH2Cl2 was added and mixt. was hydrolyzed with water and filtered, organic layer was separated, dried over Na2SO4, solvent was evapd. and residuewas recrystd. from ethanol; elem. anal.;