1,1'-bis([(diphenylchlorostannyl)methyl]dimethylsilyl)ferrocene

Base Information

Chemical Name:1,1'-bis([(diphenylchlorostannyl)methyl]dimethylsilyl)ferrocene
CAS No.:260415-55-2
Molecular Formula:C₄₀H₄₄Cl₂FeSi₂Sn₂
Molecular Weight:945.133
Hs Code.:

Synonyms:1,1'-bis([(diphenylchlorostannyl)methyl]dimethylsilyl)ferrocene

Suppliers and Price of 1,1'-bis([(diphenylchlorostannyl)methyl]dimethylsilyl)ferrocene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1,1'-bis([(diphenylchlorostannyl)methyl]dimethylsilyl)ferrocene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1,1'-bis([(diphenylchlorostannyl)methyl]dimethylsilyl)ferrocene

There total 1 articles about 1,1'-bis([(diphenylchlorostannyl)methyl]dimethylsilyl)ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 260415-49-4
1,1'-bis([(triphenylstannyl)methyl]dimethylsilyl)ferrocene

: 7553-56-2,12190-71-5,8031-47-8
iodine

: silver(I) chloride

: 591-50-4
iodobenzene

: 260415-55-2
1,1'-bis([(diphenylchlorostannyl)methyl]dimethylsilyl)ferrocene

: silver(I) iodide

Guidance literature:: In pyridine; acetonitrile; under N2 atm. I2 was added to soln. fc(SiMe2CH2SnPh3)2 in CH2Cl2 and stirred overnight, solvent and iodobenzene were removed in vacuo, residue was dissolved in CH3CN/CH2Cl, AgCl was added under exclusion of light and mixt. was stirred for 11 days; ppt. was filtered off, solvent was removed in vacuo; elem. anal.;

Reference yield: 77.0%

: 260415-45-0
FcMe₂SiCH₂Cl

: 260415-55-2
1,1'-bis([(diphenylchlorostannyl)methyl]dimethylsilyl)ferrocene

: 1,1'-bis([(((ferrocenyldimethylsilyl)methyl)diphenylstannyl)methyl]dimethylsilyl)ferrocene

Guidance literature:: With Mg; In tetrahydrofuran; under N2 atm. soln. fc(SiMe2CH2SnClPh2)2 in THF was added dropwise to soln. 2 equiv. FcMe2SiCH2MgCl prepared from FcMe2SiCH2Cl and Mg in THF, react. mixt. was heated at reflux for 2 h; THF waspartially distilled off, CH2Cl2 was added, and react. mixt. was hydrolyzed with water, mixt. was filtered, org. layer was separated and dried over Na2SO4, solvent was evapd., product was purified by size-exclusion chromy.; elem. anal.;

Reference yield: 37.0%

: 71185-81-4
1,1'-bis[(chloromethyl)dimethylsilyl]ferrocene

: 260415-55-2
1,1'-bis([(diphenylchlorostannyl)methyl]dimethylsilyl)ferrocene

: 1,1,16,16-tetraphenyl-3,3,14,14,18,18,29,29-octamethyl-3,14,18,29-tetrasila-1,16-distanna-[5,5]-ferrocenophane

Guidance literature:: With Mg; In tetrahydrofuran; under N2 atm. soln. fc(SiMe2CH2SnClPh2)2 in THF and soln. fc(SiMe2CH2MgCl)2 prepared from fc(SiMe2CH2Cl)2 and Mg in THF were added dropwise and synchronously to magnetically stirred THF, react. mixt. was heated at reflux overnight; THF was partially distilled off, CH2Cl2 was added, react. mixt. was hydrolyzed with aq. KF soln., react. mixt. was filtered, solvent was evapd., residue was dissolved in Et2O and soln. was left in refrigerator; elem. anal.;