phenyl 3-O-(methylthio)carbonyl-4-O-methyl-2-S-phenyl-2,6-di-deoxy-β-L-glucopyranosyl-(1->4)-2,3-O-isopropylidene-1-thio-α-L-rhamnopyranoside

Base Information

Chemical Name:phenyl 3-O-(methylthio)carbonyl-4-O-methyl-2-S-phenyl-2,6-di-deoxy-β-L-glucopyranosyl-(1->4)-2,3-O-isopropylidene-1-thio-α-L-rhamnopyranoside
CAS No.:327603-72-5
Molecular Formula:C₃₀H₃₈O₈S₃
Molecular Weight:622.825
Hs Code.:

Synonyms:phenyl 3-O-(methylthio)carbonyl-4-O-methyl-2-S-phenyl-2,6-di-deoxy-β-L-glucopyranosyl-(1->4)-2,3-O-isopropylidene-1-thio-α-L-rhamnopyranoside

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Chemical Property of phenyl 3-O-(methylthio)carbonyl-4-O-methyl-2-S-phenyl-2,6-di-deoxy-β-L-glucopyranosyl-(1->4)-2,3-O-isopropylidene-1-thio-α-L-rhamnopyranoside

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Technology Process of phenyl 3-O-(methylthio)carbonyl-4-O-methyl-2-S-phenyl-2,6-di-deoxy-β-L-glucopyranosyl-(1->4)-2,3-O-isopropylidene-1-thio-α-L-rhamnopyranoside

There total 3 articles about phenyl 3-O-(methylthio)carbonyl-4-O-methyl-2-S-phenyl-2,6-di-deoxy-β-L-glucopyranosyl-(1->4)-2,3-O-isopropylidene-1-thio-α-L-rhamnopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 131087-35-9
phenyl 2,3-O-isopropylidene-1-thio-α-L-rhamnopyranoside

: 333-27-7
methyl trifluoromethanesulfonate

: 327603-48-5
phenyl 4-O-methyl-2,3-O-thionocarbonyl-1-thio-α-L-rhamnopyranoside

: 327603-72-5
phenyl 3-O-(methylthio)carbonyl-4-O-methyl-2-S-phenyl-2,6-di-deoxy-β-L-glucopyranosyl-(1->4)-2,3-O-isopropylidene-1-thio-α-L-rhamnopyranoside

Guidance literature:: With 2,6-di-tert-butyl-4-methylpyridine; 4 A molecular sieve; In dichloromethane; at 20 ℃;
DOI:10.1021/ol006894+

Reference yield: 90.0%

: 131087-35-9
phenyl 2,3-O-isopropylidene-1-thio-α-L-rhamnopyranoside

: 327603-48-5
phenyl 4-O-methyl-2,3-O-thionocarbonyl-1-thio-α-L-rhamnopyranoside

: 327603-72-5
phenyl 3-O-(methylthio)carbonyl-4-O-methyl-2-S-phenyl-2,6-di-deoxy-β-L-glucopyranosyl-(1->4)-2,3-O-isopropylidene-1-thio-α-L-rhamnopyranoside

Guidance literature:: With 2,6-di-tert-butyl-4-methylpyridine; methyl trifluoromethanesulfonate; In dichloromethane; at 20 ℃;
DOI:10.1016/j.carres.2009.07.013

Reference yield:

: 327603-45-2
phenyl 4-O-methyl-1-thio-α-L-rhamnopyranoside

: 327603-72-5
phenyl 3-O-(methylthio)carbonyl-4-O-methyl-2-S-phenyl-2,6-di-deoxy-β-L-glucopyranosyl-(1->4)-2,3-O-isopropylidene-1-thio-α-L-rhamnopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 81 percent / tetrahydrofuran / 2 h / Heating

2: 90 percent / 4 Angstroem molecular sieves; 2,6-di-tert-butyl-4-methylpyridine / CH₂Cl₂ / 20 °C

With 2,6-di-tert-butyl-4-methylpyridine; 4 A molecular sieve; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ol006894+