Chemical Property of Chlorobis(cyclooctene)rhodium(I) Dimer
Chemical Property:
- Melting Point:190 ºC (dec.)
- PSA：0.00000
- LogP:12.96620
- Storage Temp.:Freezer
- Sensitive.:air sensitive, store cold
- Hydrogen Bond Donor Count:0
- Hydrogen Bond Acceptor Count:2
- Rotatable Bond Count:0
- Exact Mass:716.18690
- Heavy Atom Count:36
- Complexity:62.1
- Purity/Quality:
-
99%, *data from raw suppliers
Chlorobis(cyclooctene)rhodium(I) Dimer *data from reagent suppliers
Safty Information:
- Pictogram(s):
Xn
- Hazard Codes:Xn
- Statements:
20/21/22-36/37/38
- Safety Statements:
26-37/39
- MSDS Files:
-
SDS file from LookChem
Useful:
- Canonical SMILES:C1CCCC=CCC1.C1CCCC=CCC1.C1CCCC=CCC1.C1CCCC=CCC1.[Cl-].[Cl-].[Rh].[Rh]
- Isomeric SMILES:C1CC/C=C\CCC1.C1CC/C=C\CCC1.C1CC/C=C\CCC1.C1CC/C=C\CCC1.[Cl-].[Cl-].[Rh].[Rh]
-
Uses
Chlorobis(cyclooctene)rhodium(I),dimer can be used as a catalyst: To synthesize enantioenriched gem-diaryl sulfonates by asymmetric 1,4-addition of aryl boronic acids to α,β-unsaturated sulfonyl compounds.In direct C-arylation of N-unprotected indoles and pyrroles. In the carboxylation of arenes via C-H bond activation. Chlorobis(cyclooctene)rhodium(I) dimer is an organometallic complex used as a catalyst in the arylzincation of alkynes. It is also used as a building block for other Rh-based catalysts, such as the preparation of rhodium bis(phosphinimine)pyrrole pincer carbonyl complexes for deoxygenative metathesis of CO.
