N,N'-di-n-octyl-2-chloro-6-[(4-tert-butylphenyl)amino]-1,4,5,8-naphthalenetetracarboxylic acid diimide

Base Information

• Chemical Name: N,N'-di-n-octyl-2-chloro-6-[(4-tert-butylphenyl)amino]-1,4,5,8-naphthalenetetracarboxylic acid diimide
• CAS No.: 914455-64-4
• Molecular Formula: C₄₀H₅₀ClN₃O₄
• Molecular Weight: 672.308
• Mol file: 914455-64-4.mol

Synonyms:N,N'-di-n-octyl-2-chloro-6-[(4-tert-butylphenyl)amino]-1,4,5,8-naphthalenetetracarboxylic acid diimide

Chemical Property of N,N'-di-n-octyl-2-chloro-6-[(4-tert-butylphenyl)amino]-1,4,5,8-naphthalenetetracarboxylic acid diimide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N'-di-n-octyl-2-chloro-6-[(4-tert-butylphenyl)amino]-1,4,5,8-naphthalenetetracarboxylic acid diimide

There total 4 articles about N,N'-di-n-octyl-2-chloro-6-[(4-tert-butylphenyl)amino]-1,4,5,8-naphthalenetetracarboxylic acid diimide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

N,N'-di-(n-octyl)-2,6-dichloro-1,4,5,8-naphthalenetetracarboxylic acid diimide (510774-95-5) + 4-tert-Butylaniline (769-92-6) → N,N'-di-n-octyl-2-chloro-6-[(4-tert-butylphenyl)amino]-1,4,5,8-naphthalenetetracarboxylic acid diimide (914455-64-4)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; at 140 ℃; for 1h;

DOI:10.1021/jo0612269

Reference yield:

1,3,4,5,6,8,9,10-octachloro-4,5,9,10-tetrahydropyrene (32692-38-9) → N,N'-di-n-octyl-2-chloro-6-[(4-tert-butylphenyl)amino]-1,4,5,8-naphthalenetetracarboxylic acid diimide (914455-64-4)

Guidance literature:

Multi-step reaction with 4 steps

1.1: potassium hydroxide / ethanol / 5 h / Heating

1.2: 3.33 g / fuming nitric acid / -5 - 5 °C

2.1: 49 percent / sulfuric acid; fuming nitric acid / 100 - 130 °C

3.1: 70 percent / acetic acid / 0.17 h / Heating

4.1: 97 percent / ethyldiisopropylamine / 1 h / 140 °C

With potassium hydroxide; sulfuric acid; nitric acid; acetic acid; N-ethyl-N,N-diisopropylamine; In ethanol;

DOI:10.1021/jo0612269

Reference yield:

3,5,8,10-tetrachloropyrene-1,6-quinone (5355-83-9) → N,N'-di-n-octyl-2-chloro-6-[(4-tert-butylphenyl)amino]-1,4,5,8-naphthalenetetracarboxylic acid diimide (914455-64-4)

Guidance literature:

Multi-step reaction with 3 steps

1: 49 percent / sulfuric acid; fuming nitric acid / 100 - 130 °C

2: 70 percent / acetic acid / 0.17 h / Heating

3: 97 percent / ethyldiisopropylamine / 1 h / 140 °C

With sulfuric acid; nitric acid; acetic acid; N-ethyl-N,N-diisopropylamine;

DOI:10.1021/jo0612269

upstream raw materials:

N,N'-di-(n-octyl)-2,6-dichloro-1,4,5,8-naphthalenetetracarboxylic acid diimide

4-tert-Butylaniline

1,3,4,5,6,8,9,10-octachloro-4,5,9,10-tetrahydropyrene

2,6-dichloronaphthalene-1,4,5,8-tetracarboxylic acid bisanhydride