(4-Methylcyclohexyl)methanol

Base Information

• Chemical Name: (4-Methylcyclohexyl)methanol
• CAS No.: 34885-03-5
• Molecular Formula: C8H16 O
• Molecular Weight: 128.214
• Hs Code.: 2906199090
• European Community (EC) Number: 609-038-8
• UNII: 64PJK2GTXA,9TEH6BZ70K
• DSSTox Substance ID: DTXSID9041813,DTXSID80274141,DTXSID40274142
• Nikkaji Number: J422.320I,J100.642H,J100.643F
• Wikipedia: 4-Methylcyclohexanemethanol
• Wikidata: Q15622250,Q27263773,Q27273174
• ChEMBL ID: CHEMBL3184778
• Mol file: 34885-03-5.mol

Synonyms:4-MCHM compound;4-methylcyclohexane methanol;4-methylcyclohexanemethanol;MCHM compound

Chemical Property of (4-Methylcyclohexyl)methanol

Chemical Property:

• Vapor Pressure: 0.133mmHg at 25°C
• Refractive Index: 1.4610 to 1.4640
• Boiling Point: 192°Cat760mmHg
• PKA: 15.05±0.10(Predicted)
• Flash Point: 80.2°C
• PSA: 20.23000
• Density: 0.884g/cm³
• LogP: 1.80500
• XLogP3: 2.2
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 128.120115130
• Heavy Atom Count: 9
• Complexity: 72.6

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-Methylcyclohexanemethanol ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Alcohols and Polyols, Other
• Canonical SMILES: CC1CCC(CC1)CO

Technology Process of (4-Methylcyclohexyl)methanol

There total 25 articles about (4-Methylcyclohexyl)methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4-methylcyclohexanecarboxylic acid (4331-54-8) → (4-methylcyclohexyl)methanol (34885-03-5)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; at 0 ℃; for 6h; Inert atmosphere;

Reference yield: 52.0%

[4-(p-toluenesulfonyloxymethyl)cyclohexyl]methanol (109004-13-9) → (4-methylcyclohexyl)methanol (34885-03-5)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; for 4h; Heating;

Reference yield: 28.5%

Bis(2-Hydroxyethyl)terephthalat (959-26-2) → 4-methylbenzoic acid ethyl ester (94-08-6) + para-xylene (106-42-3) + bis-1,4-(hydroxymethyl)cyclohexane (105-08-8) + (4-methylcyclohexyl)methanol (34885-03-5) + 1,4 dimethylcyclohexane (589-90-2)

Guidance literature:

With hydrogen; at 260 ℃; for 8h; under 37503.8 Torr; Autoclave;

DOI:10.1039/c6ra04943e

upstream raw materials:

4-methylcyclohexanecarboxylic acid

methanol

methyl cyclohexane

[4-(p-toluenesulfonyloxymethyl)cyclohexyl]methanol

Downstream raw materials:

4-methylcyclohexanecarbaldehyde

1-Bromomethyl-4-methylcyclohexane

terephthalic acid 1,4-bis(4-methylcyclohexyl)methyl ester

bis((4-methylcyclohexyl)methyl) cyclohexane-1,4-dicarboxylate

Refernces

• 1、 -. "Lubricant base oil for power transmission". Page/Page column 26. . Retrieved 2021/03/17.
• 2、 Dong, Yanan,Liang, Changhai,Luo, Jingjie,Qu, Enhui,Zhou, Yixue. "Re/AC catalysts for selective hydrogenation of dimethyl 1, 4-cyclohexanedicarboxylate to 1, 4-cyclohexanedimethanol: Essential roles of metal dispersion and chemical environment". . . Retrieved 2020/06/08.